Stabilized N-alkenyllactam
AssigneeBASF SE
InventorsArnd Böttcher, Rolf Pinkos, Rudolf Erich Lorenz, Hansjörg Nickel, Jihong He
Life of this patent
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Abstract
The invention provides an N-alkenyllactam having at least a 6-membered lactam ring, stabilized by phenothiazine and/or derivatives thereof, and a process for the stabilization of N-alkenyllactams.
Claims12
A composition comprising an N—C2 to C6 alkenylcaprolactam compound wherein the C2 to C6 alkenyl group is characterized by a double bond in the α-position to the lactam nitrogen and the caprolactam ring optionally may be monosubstituted or polysubstituted by C1 to C4 alkyl groups, stabilized by a phenothiazine compound of general formula (I)
- wherein the radicals R1 to R8 independently of one another are a hydrogen atom, an unsubstituted or substituted aliphatic, aromatic or araliphatic radical having from 1 to 10 carbon atoms, an amino group, a halogen, a nitrogen group or a cyano group, with a total amount of said phenothiazine compound of the general formula (I) of 1 to 1000 ppm by weight, based on the total amount of the N-alkenyllactam.
A composition comprising an N—C2 to C6-alkenyl-2-piperidone compound wherein the C2 to C6 alkenyl group is characterized by a double bond in the α-position to the lactam nitrogen and the caprolactam ring optionally may be monosubstituted or polysubstituted by C1 to C4 alkyl groups, stabilized by a phenothiazine compound of the general formula (I)
- wherein the radicals R1 to R8 independently of one another are hydrogen atom, an unsubstituted or substituted aliphatic, aromatic or araliphatic radical having from 1 to 10 carbon atoms, an amino group, a halogen, a nitrogen group or a cyano group, with a total amount of said phenothiazine compound of the general formula (I) of 1 to 1000 ppm by weight, based on the total amount of the N-alkenyllactam.
A process for the stabilization of an N—C2- to C6-alkenylcaprolactam compound wherein the C2 to C6 alkenyl group is characterized by a double bond in the α-position to the lactam nitrogen and the caprolactam ring optionally may be monosubstituted or polysubstituted by C1 to C4 alkyl groups, wherein the N—C2-to C6-alkenylcaprolactam compound is mixed with a phenothiazine compound of the general formula (I)
- wherein the radical R1 to R8 independently of one another are a hydrogen atom, an unsubstituted or substituted aliphatic, aromatic or araliphatic radical having from 1 to 10 carbon atoms, an amino group, a halogen, a nitrogen group or a cyano group, with a total amount of said phenothiazine compound of the general formula (I) of 1 to 1000 ppm by weight, based on the total amount of the N-alkenyllactam.
A process for the stabilization of an N—C2- to C6-alkenyl-2-piperidone compound wherein the C2 to C6 alkenyl group is characterized by a double bond in the α-position to the lactam nitrogen and the caprolactam ring optionally may be monosubstituted or polysubstituted by C1 to C4 alkyl groups, wherein the N—C2- to C6-alkenylcaprolactam compound is mixed with a phenothiazine compound of the general formula (I)
- wherein the radicals R1 to R8 independently of one another are a hydrogen atom, an unsubstituted or substituted aliphatic, aromatic or araliphatic radical having from 1 to 10 carbon atoms, an amino group, a halogen, a nitrogen group or a cyano group, with a total amount of said phenothiazine compound of the general formula (I) of 1 to 1000 ppm by weight, based on the total amount of N-alkenyllactam.
Dependencies are inferred from the claim text.