Branched polyacetal resin composition
AssigneePolyplastics Co., Ltd.
InventorsKuniaki Kawaguchi, Hidetoshi Okawa, Yoshihisa Tajima
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Abstract
To offer a resin material in which various properties such as excellent appearance and rigidity inherent to a polyacetal resin are maintained and a weather (light) resistance is improved. That is, a branched polyacetal resin composition comprising 100 parts by weight of a branched polyacetal copolymer (A) having an oxymethylene group as the main repeating unit and having a branching unit represented by the following formula (I), 0.01 to 5 parts by weight of a weather (light) resistant stabilizer (B) and 0.01 to 5 parts by weight of a hindered amine substance (C): wherein m and n each is an integer of 0 to 5; the sum of m+n is 1 to 5; and R is a monovalent organic group having a molecular weight of 40 to 1000.
Claims5
A branched polyacetal resin composition, comprising:
- (A) 100 parts by weight of a branched polyacetal copolymer which is the copolymeriziation reaction product of:
- (a) 100 parts by weight of trioxane,
- (b) 0.001 to 10 parts by weight of a monofunctional glycidyl compound, and
- (c) 0.1 to 20 parts by weight of a cyclic ether compound which is copolymerizable with trioxane, wherein
- said branched polyacetal copolymer has an oxymethylene group as the main repeating unit and a branching unit represented by the following formula (I):
- wherein m and n each is an integer of 0 to 5;
- the sum of m+n is 1 to 5;
- and R is a monovalent organic group having a molecular weight of 40 to 1000;
- (B) 0.01 to 5 parts by weight of a weather (light) resistant stabilizer;
- and
- (C) 0.01 to 5 parts by weight of a hindered amine substance;
- and wherein
- the monofunctional glycidyl compound (b) is selected from the glycidyl ether compounds represented by the following formulae (II), (III) and (IV):
- wherein R1 is a C1-12 alkyl group, a substituted alkyl group, an alkoxy group, an aryl group, a substituted aryl group or halogen;
- and n is an integer of 0 to 5 and, when n is 2 or more, the R1s may be the same or different:
- wherein R2 is a C1-30 alkylene group, a substituted alkylene group or a polyalkylene oxide glycol residue;
- R3 is a C1-12 alkyl group, a substituted alkyl group, an alkoxy group, an aryl group, a substituted aryl group or halogen;
- and n is an integer of 0 to 5 and, when n is 2 or more, the R3s may be the same or different:
- wherein R4 is a C1-30 alkylene group;
- n is an integer of 0 to 20;
- and R5 is a C1-30 alkyl group, a C2-20 alkenyl group or an alkynyl group.
Dependencies are inferred from the claim text.