Copolyesters and fibrous materials formed therefrom
AssigneeEastman Chemical Company
InventorsWilliam A. Haile, Leron R. Dean, Richard L. McConnell, Mark E. Tincher, Alan W. White, Charles M. Buchanan
Life of this patent
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Abstract
This invention relates to binary blends of cellulose esters and aliphatic-aromatic copolyesters, cellulose esters and aliphatic polyesters as well as ternary blends of cellulose esters and/or aliphatic polyesters and/or aliphatic-aromatic copolyesters and/or polymeric compounds as well as fibers, nonwovens, molded objects, and films prepared therefrom.
Claims27
A fiber prepared from a copolyester having a dicarboxylic acid component and a diol component, the copolyester comprising repeat units of the following structures:
- [Brketopenst]O—(R11)—O—C(O)—(R13)—C(O)[Brketclosest]
- and
- [Brketopenst]O—(R12)—O—C(O)—(R14)—C(O)[Brketclosest]
- wherein R11 and R12 are selected from the group consisting of C2-C12 alkylene, C5-C10 cycloalkylene, C2-C12 oxyalkylene and mixtures thereof;
- wherein the dicarboxylic acid component contains an aliphatic dicarboxylic acid R13, and an aromatic or cycloaliphatic dicarboxylic acid component R14;
- wherein R13 is selected from the group consisting of C0-C10 alkylene or C2-C4 oxyalkylene and mixtures thereof, wherein the mole % of R13 ranges from about 45 to 95% of the dicarboxylic acid component;
- and R14 is selected from the group consisting of C6-C12 aryl and cycloaliphatic and mixtures thereof wherein the mole % of R14 is from about 5 to 55% of the dicarboxylic acid component;
- wherein the polyester is formed in the presence of 0 to about 20 mole % of at least one amine compound selected from the group consisting of aminoalcohols, aminoacids, diamines, lactams and mixtures thereof;
- wherein the copolyester has a melting point ranging from about 75° C. to about 160° C.;
- and wherein the fiber is in a form selected from the group consisting of melt blown, spunbond, spun fibers and mixtures thereof.
A composition comprising at least two polyesters, the first polyester comprising polylactic acid and the second polyester composition a dicarboxylic acid component and a diol component, the polyester comprising repeat units of the following structures:
- [Brketopenst]O—(R11)—O—C(O)—(R13)—C(O)[Brketclosest]
- and
- [Brketopenst]O—(R12)—O—C(O)—(R14)—C(O)[Brketclosest]
- wherein R11 and R12 are selected from the group consisting of C2-C12 alkylene, C5-C10 cycloalkylene, C2-C12 oxyalkylene and mixtures thereof;
- wherein the dicarboxylic acid component contains an aliphatic dicarboxylic acid R13, and an aromatic or cycloaliphatic dicarboxylic acid component R14;
- wherein R13 is selected from the group consisting of C0-C10 alkylene or C2-C4 oxyalkylene and mixtures thereof, wherein the mole % of R13 ranges from about 45 to 95% of the dicarboxylic acid component;
- and R14 is selected from the group consisting of C6-C12 aryl and cycloaliphatic and mixtures thereof wherein the mole % of R14 is from about 5 to 55% of the dicarboxylic acid component.
Dependencies are inferred from the claim text.