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US 6,555,709 B1Granted
Aromatic amides, their preparation process and their use as pesticides
AssigneeHoechst Schering AgrEvo GmbH
InventorsAgnés Brouillard, Jacques Demassey, Philippe Dutheil, John Weston
Life of this patent
Estimating the term…
Abstract
Aromatic amides, their preparation process and their use as pesticides.
Claims29
A compound of the formula
- in which
- a, b, c and d, identical to or different from one another, represent a hydrogen atom, a halogen atom, an alkyl, alkenyl or alkynyl, O-alkyl, O-alkenyl or O-alkynyl, S-alkyl, S-alkenyl or S-alkynyl radical containing up to 8 carbon atoms, optionally substituted by one ore more halogen atoms, a C≡N, NO2 or NH2 radical, the substituents a, b, c, and d being able to form between themselves rings, which either contain or do not contain one or more hetero atoms, and which are substituted or unsubstituted,
- wherein
- i) when Y and W, identically or different, represent
- where
- e′ is a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an optionally halogen substituted C1-C8 alkyl radical,
- X represents
- where
- g and h identical or different represent a hydrogen atom, a halogen atom, a free etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in 2-position belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atoms;
- and
- q is a C═ radical or a CD radical in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with the carbon atom which carries it and one of the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- ii) when Y and W identical of different represent
- where
- e and f, identical or different, are a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms;
- X represents
- where
- g′ is identical or different is a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in the 2-position belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atoms;
- and
- q represents a C═ radical or a CD radical, in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with the carbon atom which carries it and one of the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- or
- iii) Y and W identical or different represent
- where
- e and f, identical or different, are a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms;
- X represents
- where
- g and h identically or different represent a hydrogen atom, a halogen atom, a free etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in position 2 belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atom;
- and
- q represents a C═ radical or a CD radical in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with the carbon atom which carries it and one of the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- n represents an integer varying from 0 to 8,
- Z represents
- in which
- l and k, identical or different, represent a hydrogen atom, a halogen atom, a C≡N radical, a free, etherified or esterified hydroxyl radical, an SR′ radical wherein R′ is an organic group containing up to 8 carbon atoms or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or Z represents an oxygen, sulfur, nitrogen atom, a C═O or C═S radical, it being understood that if n is greater than 1, Z can take different values,
- R represents an oxygen or sulfur atom;
- R1 and R2, identical to or different from one another, represent a hydrogen atom, a linear, branched or cyclic, saturated or unsaturated, optionally substituted alkyl, CO-alkyl, CONH-alkyl or CO2 alkyl radical, said alkyl radical, optionally interrupted by one or more heteroatoms and containing up to 8 carbon atoms, or an optionally substituted aryl or heteroaryl radical,
- the —C—(Z)n chain is fixed in position 3 or 4 of the benzamide, the dotted lines representing one or more optional double bonds, in all its possible isomeric forms as well as mixtures of said forms.
32 more elements
A compound of the formula
- in which
- a, b, c, and d identical to or different from one another, represent a hydrogen atom, a halogen atom, an alkyl, alkenyl or alkynyl, O-alkyl, O-alkenyl or O-alkynyl, S-alkyl, S-alkenyl or S-alkynyl radical containing up to 8 carbon atoms, optionally substituted by one ore more halogen atoms, a C≡N, NO2 or NH2 radical, the substituents a, b, c, and d being able to form between themselves rings, which either contain or do not contain one or more hetero atoms, and which are substituted or unsubstituted;
- Y and W, identical to or different from one another, both represent a radical of the formula
- or
- both represent a radical of the formula
- in which
- e, f, and e′, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms;
- X represents a radical of the formula
- or a radical of the formula
- in which
- g, h, and g′, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in 2-position belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atoms;
- q represents a C═ radical or a CD radical, in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with carbon atom which carries it and one of the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- n represents an integer varying from 0 to 8,
- Z represents
- in which
- l and k, identical
- or different, represent a hydrogen atom, a halogen atom, a C≡N radical, a free, etherified or esterified hydroxyl radical, an SR′ radical wherein R′ is an organic group containing up to 8 carbon atoms or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or Z represents an oxygen, sulfur, nitrogen atom, a C═O or C═S radical, it being understood that if n is greater than 1, Z can take different values,
- R represents an oxygen or sulfur atom;
- R1 and R2, identical to or different from one another, represent a hydrogen atom, a linear, branched or cyclic, saturated or unsaturated, optionally substituted alkyl, CO-alkyl, CONH-alkyl or CO2-alkyl radical, said alkyl radical, where said alkyl radical is optionally interrupted by one or more heteroatoms and contains up to 8 carbon atoms, or an optionally substituted aryl or heteroaryl radical,
- the —C—(Z)n chain is fixed in position 3 or 4 of the benzamide, the dotted lines representing one or more optional double bonds, in all its possible isomeric forms as well as its mixtures
- wherein at least one of the substituents a, b, c, or d represents a halogen atom.
18 more elements
A pesticidal composition for combating harmful arthropods and/or helminthes which comprises at least one compound of the formula
- in which
- a, b, c, and d, identical to or different from one another, represent a hydrogen atom, a halogen atom, an alkyl, alkenyl or alkynyl, O-alkyl, O-alkenyl or O-alkynyl, S-alkyl, S-alkenyl or S-alkynyl radical containing up to 8 carbon atoms, optionally substituted by one or more halogen atoms, a C≡N, NO2 or NH2 radical, the substituents a, b, c, and d being able to form between themselves rings, which either contain or do not contain one or more hetero atoms, and which are substituted or unsubstituted;
- wherein
- i) when Y and W, identically or different, represent
- where
- e′ is a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an optionally halogen substituted C1-C8 alkyl radical,
- X represents
- where
- g and h identical or different represent a hydrogen atom, a halogen atom, a free etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in 2-position belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atoms;
- and
- q is a C═ radical or a CD radical in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with the carbon atom which carries it and one of the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- ii) when Y and W identical of different represent
- where
- e and f, identical or different, are a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms;
- X represents
- where
- g′ is identical or different is a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in the 2-position belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atoms;
- and
- q represents a C═ radical or a CD radical, in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with the carbon atom which carries it and one of the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- or
- iii) Y and W identical or different represent
- where
- e and f, identical or different, are a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms;
- X represents
- where
- g and h identically or different represent a hydrogen atom, a halogen atom, a free etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in position 2 belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atom;
- and
- q represents a C═ radical or a CD radical in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with the carbon atom which carries it and one of the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- n represents an integer varying from 0 to 8,
- Z represents
- in which
- l and k, identical or different, represent a hydrogen atom, a halogen atom, a C≡N radical, a free, etherified or esterified hydroxyl radical, an SR′ radical wherein R′ is an organic group containing up to 8 carbon atoms or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or Z represents an oxygen, sulfur, nitrogen atom, a C═O or C═S radical, it being understood that if n is greater than 1, Z can take different values,
- R represents an oxygen or sulfur atom;
- R1 and R2, identical to or different from one another, represent a hydrogen atom, a linear, branched or cyclic, saturated or unsaturated, optionally substituted alkyl, CO-alkyl, CONH-alkyl or CO2-alkyl radical, where said alkyl radical is optionally interrupted by one or more heteroatoms and contains up to 8 carbon atoms, or an optionally substituted aryl or heteroaryl radical;
- the —C—(Z)n chain is fixed in position 3 or 4 of the benzamide, the dotted lines representing one or more optional double bonds, in all its possible isomeric forms as well as its mixtures
- and an inert excipient.
33 more elements
A pesticidal composition for combating harmful arthropods and/or helminthes which comprises at least one compound of the formula
- 4-[(6-chloro-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(5-bromo-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(6-bromo-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(6-bromo-3,4-dihydro-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(6-chloro-1,2,3,4-tetrahydro-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(6-chloro-3,4-dihydro-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(6,7-dibromo-3,4-dihydro-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(6,7-dibromo-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(5,6-dichloro-1-fluoro-1,2,3,4-tetrahydro-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(5,6-dichloro-3,4-dihydro-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(6,7-dichloro-1,2,3,4-tetrahydro-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(6,7-dichloro-2-naphthalenyl)methyl]-N-(2-methylphenyl)benzamide,
- 4-[(6,7-dichloro-2-naphthalenyl)methyl]-N-(2-dimethylpropyl)benzamide,
- 4-[(6-chloro-2-naphthalenyl)methyl]-N-(1,2-dimethylpropyl)benzamide.
11 more elements
A compound of the formula
- in which
- a, b, c and d, identical to or different from one another, represent a hydrogen atom, a halogen atom, an alkyl, alkenyl or alkynyl, O-alkyl, O-alkenyl or O-alkynyl, S-alkyl, S-alkenyl or S-alkynyl radical containing up to 8 carbon atoms, optionally substituted by one or more halogen atoms, a C≡N, NO2 or NH2 radical, the substituents a, b, c and d being able to form between themselves rings, which either contain or do not contain one or more hetero atoms, and which are substituted or unsubstituted,
- Y and W are identical to or different from one another, and both represent
- in which
- e and f, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms;
- X represents
- or
- in which
- g, h and g′, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in the 2-position belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atoms;
- q represents a C═ radical or a CD radical, in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with the carbon atom which carries it and on eof the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- n represents an integer varying from 0 to 8,
- Z represents
- l and k, identical or different, represent a hydrogen atom, a halogen atom, a C≡N radical, a free, etherified or esterified hydroxyl radical, an SR′ radical wherein R′ is an organic group containing up to 8 carbon atoms or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or Z represents an oxygen, sulfur, nitrogen atom, C═O or C═S radical, it being understood that if n is greater than 1, Z can take different values,
- R represents an oxygen or sulfur atom;
- and
- D′ represents an hydroxy radical, a halogen atom, an alkoxy radical containing up to 4 carbon atoms or a —P(O)(Oφ)NHφ group in which φ represents a phenyl group.
13 more elements
A method for combatting and/or eradicating infestations of pests in an animal, plant or stored product which comprises administering to said animal or applying to said plant or stored product or to a locality where said plant or stored product resides, an effective amount of a compound of the formula
- in which
- a, b, c, and d, identical to or different from one another, represent a hydrogen atom, a halogen atom, an alkyl, alkenyl or alkynyl, O-alkyl, O-alkenyl or O-alkynyl, S-alkyl, S-alkenyl or S-alkynyl radical containing up to 8 carbon atoms, optionally substituted by one or more halogen atoms, a C≡N, NO2 or NH2 radical, the substituents a, b, c, and d being able to form between themselves rings, which either contain or do not contain one or more hetero atoms, and which are substituted or unsubstituted;
- Y and W, identical to or different from one another,
- both represent
- or both represent
- in which
- e, f, and e′, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms;
- X represents
- or
- in which
- g, h, g′, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in 2-postion belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atoms;
- q represents a C═ radical or a CD radical, in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with carbon atom which carries it and one of the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- n represents an integer varying from 0 to 8,
- Z represents
- in which l and k, identical
- or different, represent a hydrogen atom, a halogen atom, a C≡N radical, a free, etherified or esterified hydroxyl radical, an SR′ radical wherein R′ is an organic group containing up to 8 carbon atoms or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or Z represents an oxygen, sulfur, nitrogen atom, a C═O or C═S radical, it being understood that if n is greater than 1, Z can take different values,
- R represents an oxygen or sulfur atom;
- R1 and R2, identical to or different from one another, represent a hydrogen atom, a linear, branched or cyclic, saturated or unsaturated, optionally substituted alkyl, CO-alkyl, CONH-alkyl or CO2 alkyl radical, said alkyl radical, optionally interrupted by one or more heteroatoms and containing up to 8 carbon atoms, or an optionally substituted aryl or heteroaryl radical,
- the —C—(Z)n chain is fixed in position 3 or 4 of the benzamide, the dotted lines representing one or more optional double bonds, in all its possible isomeric forms as well as its mixtures wherein at least one of the substituents a, b, c or d represents a halogen atom,
- whereby said pest is an anthropod, helminth, mollusk a combination of at least two of the the foregoing.
17 more elements
A compound of the formula
- in which
- a, b, c and d, identical to or different from one another, represent a hydrogen atom, a halogen atom, an alkyl, alkenyl or alkynyl, O-alkyl, O-alkenyl or O-alkynyl, S-alkyl, S-alkenyl or S-alkynyl radical containing up to 8 carbon atoms, optionally substituted by one or more halogen atoms, a C≡N, NO2 or NH2 radical, the substituents a, b, c and d being able to form between themselves rings, which either contain or do not contain one or more hetero atoms, and which are substituted or unsubstituted,
- Y and W are identical to or different from one another, and both represent
- in which
- e, f, and e′, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms;
- X represents
- or
- in which
- g, h and g′, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in the 2-position belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atoms;
- q represents a C═ radical or a CD radical, in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with the carbon atom which carries it and on eof the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- n represents an integer varying from 0 to 8,
- Z represents
- in which
- l and k, identical or different, represent a hydrogen atom, a halogen atom, a C≡N radical, a free, etherified or esterified hydroxyl radical, an SR′ radical wherein R′ is an organic group containing up to 8 carbon atoms or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or Z represents an oxygen, sulfur, nitrogen atom, C═O or C═S radical, it being understood that if n is greater than 1, Z can take different values,
- R represents an oxygen or sulfur atom;
- R1 and R2 identical to or different from one another, represent a hydrogen atom, a linear, branched or cyclic, saturated or unsaturated, optionally substituted alkyl, CO-alkyl, CONH-alkyl or CO2 alkyl radical, said alkyl radical optionally interrupted by one or more heteroatoms, containing up to 8 carbon atoms, or an optionally substituted aryl or heteroaryl radical,
- the —C—(Z)n chain is fixed in position 3 or 4 of the benzamide, the dotted lines representing one or more optional double bonds.
14 more elements
A method for protecting crops or treating premises used for storing said crops from insects, acarides and nematodes which comprises applying to said crops or to said premises an effective amount of a compound of the formula
- in which
- a, b, c, and d, identical to or different from one another, represent a hydrogen atom, a halogen atom, an alkyl, alkenyl or alkynyl, O-alkyl, O-alkenyl or O-alkynyl, S-alkyl, S-alkenyl or S-alkynyl radical containing up to 8 carbon atoms, optionally substituted by one or more halogen atoms, a C≡N, NO2 or NH2 radical, the substituents a, b, c, and d being able to form between themselves rings, which either contain or do not contain one or more hetero atoms, and which are substituted or unsubstituted,
- Y and W, identical to or different from one another,
- both represent
- in which
- e, f, and e′, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms;
- X represents
- or
- in which
- g, h, g′, identical or different, represent a hydrogen atom, a halogen atom, a free, etherified or esterified hydroxyl radical, or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or X represents a C═O radical, an oxygen atom or a nitrogen atom, or X forms with the carbon in 2-position belonging to radical q an epoxy bridge, a cyclic hydrocarbonated radical optionally substituted by one or more halogen atoms;
- g represents a C═ radical or a CD radical, in which D represents a hydrogen atom, a halogen atom or an alkyl or alkoxy radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or D forms with carbon atom which carries it and one of the carbon atoms adjacent to it a carbon-carbon double bond, an epoxy radical, a cyclic hydrocarbonated radical, optionally substituted by one or more halogen atoms;
- n represents an integer varying from 0 to 8,
- Z represents
- in which
- l and k, identical
- or different, represent a hydrogen atom, a halogen atom, a C≡N radical, a free, etherified or esterified hydroxyl radical, an SR′ radical wherein R′ is an organic group containing up to 8 carbon atoms or an alkyl radical containing up to 8 carbon atoms optionally substituted by one or more halogen atoms, or Z represents an oxygen, sulfur, nitrogen atom, a C═O or C═S radical, it being understood that if n is greater than 1, Z can take different values,
- R represents an oxygen or sulfur atom;
- R1 and R2, identical to or different from one another, represent a hydrogen atom, a linear, branched or cyclic, saturated or unsaturated, optionally substituted alkyl, CO-alkyl, CONH-alkyl or CO2 alkyl radical, said alkyl radical, optionally interrupted by one or more heteroatoms and containing up to 8 carbon atoms, or an optionally substituted aryl or heteroaryl radical,
- the —C—(Z)n chain is fixed in position 3 or 4 of the benzamide, the dotted lines representing one or more optional double bonds, in all its possible isomeric forms as well as mixtures of said forms.
16 more elements
Dependencies are inferred from the claim text.