Multifunctional allyl carbamates and coatings therefrom
AssigneeArco Chemical Technology, L.P.
InventorsDaniel B. Pourreau, Peter J. Whitman, Stephen L. Goldstein, Stephen H. Harris
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Abstract
Allyl carbamates are disclosed. The allyl carbamates are prepared by reacting an isocyanate with an allylic alcohol or alkoxylated allylic alcohol. Suitable isocyanates are selected from hexamethylene diisocyanate (HDI), HDI biuret, dimer, HDI trimer, HDI allophanate, isophorone diisocyanate (IPDI), IPDI trimer, IPDI allophanate, bis(isocyanatocyclohexyl)methane, and mixtures thereof. The allyl carbamates have at least two allyl functional groups per molecule. UV-curable and air-drying coatings formulated from the allyl carbamates show excellent chemical resistance and physical properties.
Claims4
A UV-curable powder coating composition comprising an allyl carbamate which is a solid at 25° C. and is a reaction product of
- (a) an isocyanate selected from the group consisting of hexamethylene diisocyanate (HDI), HDI biuret, HDI dimer, HDI trimer, HDI allophanate, isophorone diisocyanate (IPDI), IPDI trimer, IPDI allophanate, bis(isocyanatocyclohexyl)methane, and mixtures thereof;
- and
- (b) an allylic alcohol having the structure:
- in which R is hydrogen, a C1 to C10 alkyl group, or a C6 to C10 aryl or alkylaryl group;
- wherein the allyl carbamate has at least two allyl functional groups.
Dependencies are inferred from the claim text.