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US 6,552,210 B1Granted
Transition metal compound containing cationic groups which is used as an olefin polymerization catalyst component
AssigneeTargor GmbH
InventorsMarkus Göres, Hans Bohnen
Life of this patent
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Abstract
Specifically substituted metallocenes can be used in the polymerization of olefins. The novel compounds contain a cationic group as substituents and are suitable as constituents of a catalyst system for the polymerization of olefins.
Claims8
A compound of the formula (I)
- where
- M1 is a transition metal of group 4 of the Periodic Table of the Elements,
- R1 and R2 are identical or different and are each a hydrogen atom, a halogen atom or a C1-C20 group,
- R3 are identical or different and are each a hydrogen atom, a halogen atom or a C1-C40 group, and two radicals R3 may form a monocyclic or polycyclic ring system which may in turn be substituted, where at least one of the radicals R3 comprises a cationic group (—DEL)+Y−
- where
- D is an atom of group 15 or 16 of the Periodic Table of the Elements,
- E are identical or different and are each a hydrogen atom or a C1-C20 group, and two radicals E may form a monocyclic or polycyclic ring system which may in turn be substituted,
- L is 3 when D is an atom of group 15 of the Periodic Table of the Elements and is 2 when D is an atom of group 16 of the Periodic Table of the Elements,
- Y is halogen C1-C10-alkylsulfonate, C1-C10-haloalkylsulfonate, C6-C20-alkylsulfonate, C6-C20-haloarylsulfonate, C1-C20-alkylarylsulfonate, C1-C20-haloalkylcarboxylate, C1-C10-alkyl sulfate, tetrafluoroborate, hexafluorophosphate, hexafluoroantimonate or hexafluoroarsenate,
- m is an integer less than or equal to 4 and greater than or equal to 1,
- m′ is an integer smaller than or equal to 4 and greater than or equal to 1,
- k is zero or 1, where the metallocene is unbridged when k=0 and is bridged when k=1,
- A is a bridge of the formula
- or ═BR4, AIR4, —S—, —SO—, —SO2—, ═NR4, ═PR4, ═P(O)R4, o-phenylene, 2,2′-biphenylene, where
- M2 is Carbon, silicon, germanium, tin, nitrogen or phosphorus,
- o is 1, 2, 3 or 4,
- R4 and R5 are identical or different and are each a hydrogen atom, halogen or a C1-C20 group, and R4 and R5 may form a monocyclic or polycyclic ring system.
14 more elements
Dependencies are inferred from the claim text.