Propylene terpolymers
AssigneeBorealis Technology Oy
InventorsKauno Alastalo, Bo Malm, Päivi Pitkänen, Mika Meller, Anne Britt Bjåland, Nina Ackermans, Kshama Motha
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AssigneeBorealis Technology Oy
InventorsKauno Alastalo, Bo Malm, Päivi Pitkänen, Mika Meller, Anne Britt Bjåland, Nina Ackermans, Kshama Motha
Estimating the term…
A process for producing terpolymers of propylene, comprising a) feeding into a slurry reactor a reaction mixture containing 50-85 w-% of propylene, 1-10 w-% of ethylene, 15-40 w-% of another C4-C8 alpha-olefin, a catalyst system maintaining olefin polymerization at said temperature conditions, and optionally hydrogen, b) polymerizing said reaction mixture at a temperature of lower than 70° C. a sufficient time to obtain a propylene terpolymer amounting to 50-99 w-% of the end product, c) transferring said reaction mixture into a gas phase reactor operating at a pressure of higher than 5 bars, preferably higher than 10 bars, optionally adding 0-30 w-% of ethylene, 0-10 w-% of another C4-C8 alpha-olefin, 0-40 w-% of propylene and optionally hydrogen, and d) continuing polymerization in said gas phase reactor for obtaining a propylene terpolymer amounting to 1-50 wt-% of the end product. The terpolymer has a melting temperature a less than 135° C., preferably less than 132° C., and it can be used for manufacturing films having good sealing properties.
A film-making terpolymer of propylene, comprising a mixture of different propylene terpolymer compositions and further comprising comonomer units derived from ethylene and at least one alpha-olefin selected from the group of C4-C8 alpha-olefins, the weight ratio of ethylene to the C4-C8 alpha-olefin(s) being less than 0.3 and the hexane solubles fraction is less than 6.5% calculated from the total weight of the terpolymer.
Dependencies are inferred from the claim text.