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US 6,551,666 B2Granted
Cyclohexane derivatives and liquid-crystalline medium
AssigneeMerck Patent Gesellschaft mit
InventorsPeer Kirsch, Joachim Krause, Michael Heckmeier
Life of this patent
Estimating the term…
Abstract
The invention relates to cyclohexane derivatives of the formula I in which n, m, p, R1, X1, X2, Z1, Z2, Z3, A1 A2 and Y are as defined above.
Claims10
A cyclohexane compound of formula I
- wherien
- Y is alkyl or alkoxy having 1 to 10 carbon atoms which is optionally at least monosubstituted by halogen, is alkenyl or alkenyloxy having 2 to 10 carbon atoms which is optionally at least monosubstituted by —CN, —CF3 or —F, or is —CN, —F, —OCHF2, —OCF3, —OCHFCF3 or —OCF2CF3,
- one of X1 and
- X2 is CF3, CHF2, CH2F, OCHF2, OCF3, SF5 or an alkyl radical having 2 to 10 carbon atoms which is monosubstituted or polysubstituted by fluorine or chlorine, and one of X1 or X2 in each cyclohexane ring is H,
- R1 is H, alkyl or alkenyl having 1 to 12 carbon atoms which is optionally monosubstituted by CN or CF3 or at least monosubstituted by halogen, where one or more non-adjacent CH2 groups is optionally independently replaced by
- A1 and A2, are each independently
- a) a trans-1,4-cyclohexylene radical, in which at least one or more non-adjacent CH2 group is optionally independently replaced by —O— or —S—,
- b) a 1,4-phenylene radical, in which, one or two CH groups is optionally replaced by N,
- c) 1,4-bicyclo[2.2.2]octylene, piperidine-1,4-diyl, naphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl, or
- d) 1,4-cyclohexenylene,
- wherein a), b) and d) is optionally substituted by CN, Cl or F,
- Z1, Z2 are each independently, —CO—O—,
- and Z3—O—CO—, CH2O—, —O—, —O—CH2—, —CH2CH2—, —CH═CH—, —C≡C—, —CF2CF2——CF2O—, —OCF2— or a single bond,
- n and m, are each independently 0, 1, 2 or 3,
- and
- p is 0, 1, 2 or 3,
- where
- m+n+p is 1, 2, 3 or 4.
15 more elements
Dependencies are inferred from the claim text.