Modified polyolefin resin composition
AssigneeMitsubishi Chemical Corporation
InventorsTsukasa Satou, Yuuichi Shimizu, Satoru Yamamoto, Kazunori Yano
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Abstract
A modified polyolefin resin composition according to the present invention comprises a polyolefin resin modified with an unsaturated carboxylic acid and is suitable for imparting a good adhension property. The adhesion property of the modified polyolefin resin composition is largely influenced by the graft structure composed of the unsaturated carboxylic acid polyolefin resin, which is produced upon grafting the polyolefin resin with the unsaturated carboxylic acid
Claims6
An unsaturated carboxylic acid-modified polyolefin resin composition consisting essentially of polypropylene modified with an unsaturated carboxylic acid and satisfying the following formulae (I) and (II) with respect to a small-angle X-ray scattering which is incident perpendicularly on said composition melted at 170° C.:
- when a wave number vector (s) is in the range of 0.003 Å−1 to 0.006 Å−1,
- −5.0≦A≦−3.0 (I)
- wherein A represents a gradient of a characteristic curve obtained by plotting logarithms of a corrected scattering intensity (I1(s)) on Y (ordinate) axis and the wave number vector (s) on X (abscissa) axis, and wherein said corrected scattering intensity (I1(s)) is a value obtained by subtracting a product of an air scattering intensity and an X-ray transmittance and a background intensity based on thermal diffuse scattering, from the small-angle X-ray scattering intensity:
- 0.001≧Qn/P≧0.0001 (II)
- wherein Qn and P are values calculated from the following formulae (1) and (2):
- Qn = ∫ 0.003 0.007 s 2 I 1 ( s ) ⅆ s / ∫ 0.02 0.04 s 2 I 2 ( s ) ⅆ s ( 1 )
- wherein s is a wave number vector, I1(s) is a corrected scattering intensity, and I2(s) is a scattering intensity at 170° C. of polyolefin before modification, P = ∫ 0.003 0.007 s 2 I 1 ( s ) ⅆ s / M ( 2 )
- wherein M is an average value of s4I1(s) when s is in the range of 0.003 Å−1 to 0.004 Å−1.
Dependencies are inferred from the claim text.