Process for reducing concentration of carbon monoxide in hydrogen-containing gas
AssigneeMitsubishi Gas Chemical Company, Inc.
InventorsKoki Takamura, Yasushi Hiramatsu
Life of this patent
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Abstract
In the present invention, carbon monoxide in the hydrogen-containing gas is contacted with oxygen in the presence of a catalyst comprising platinum and at least one metal selected from the group consisting of cobalt, nickel, copper and manganese.
Claims24
A process for reducing a concentration of carbon monoxide in a hydrogen-containing gas adapted for use in fuel cells, comprising the step of contacting the carbon monoxide in said hydrogen-containing gas adapted for use in fuel cells with oxygen at a temperature of 30 to 200° C. in the presence of a catalyst consisting of cobalt and platinum, supported on a carrier, such that the amount of the oxygen contacted is 0.5 to 2 times the amount of the carbon monoxide contained in the hydrogen-containing gas.
A process for reducing a concentration of carbon monoxide in a hydrogen-containing gas adapted for use in fuel cells, comprising the step of contacting the carbon monoxide in said hydrogen-containing gas adapted for use in fuel cells with oxygen at a temperature of 40 to 200° C. in the presence of a catalyst consisting of nickel and platinum, supported on a carrier, such that the amount of the oxygen contacted is 0.5 to 2 times the amount of the carbon monoxide contained in the hydrogen-containing gas.
A process for reducing a concentration of carbon monoxide in a hydrogen-containing gas adapted for use in fuel cells, comprising the step of contacting the carbon monoxide in said hydrogen-containing gas adapted for use in fuel cells with oxygen at a temperature of 100 to 200° C. in the presence of a catalyst consisting of copper and platinum, supported on a carrier, such that the amount of the oxygen contacted is 0.5 to 4 times the amount of the carbon monoxide contained in the hydrogen-containing gas.
A process for reducing a concentration of carbon monoxide in a hydrogen-containing gas adapted for use in fuel cells, comprising the step of contacting the carbon monoxide in said hydrogen-containing gas adapted for use in fuel cells with oxygen at a temperature of 40 to 200° C. in the presence of a catalyst consisting of manganese and platinum, supported on a carrier, such that the amount of the oxygen contacted is 0.5 to 2 times the amount of the carbon monoxide contained in the hydrogen-containing gas.
A process for reducing a concentration of carbon monoxide in a hydrogen-containing gas adapted for use in fuel cells, comprising the steps of contacting the carbon monoxide in said hydrogen-containing gas adapted for use in fuel cells with oxygen at a temperature of 40 to 200° C. in the presence of a catalyst consisting of (a) at least one selected from the group consisting of cobalt, nickel, copper and manganese, and also (b) platinum, the catalyst being supported on a carrier, such that the amount of the oxygen contacted is 0.5 to 2 times the amount of the carbon monoxide contained in the hydrogen-containing gas.
A process for reducing a concentration of carbon monoxide in a hydrogen-containing gas adapted for use in fuel cells, comprising the steps of contacting the carbon monoxide in said hydrogen-containing gas adapted for use in fuel cells with oxygen at a temperature of 40 to 200° C. in the presence of a catalyst consisting of (a) at least one selected from the group consisting of cobalt, nickel, copper and manganese, and also (b) platinum, the catalyst being in a form of a coprecipitated catalyst, such that the amount of the oxygen contacted is 0.5 to 2 times the amount of the carbon monoxide contained in the hydrogen-containing gas.
A process for reducing a concentration of carbon monoxide in a hydrogen-containing gas adapted for use in fuel cells, comprising the steps of contacting the carbon monoxide in said hydrogen-containing gas adapted for use in fuel cells with oxygen at a temperature of 40 to 200° C. in the presence of a catalyst, the catalyst consisting of (a) at least one selected from the group consisting of cobalt, nickel, copper and manganese, and also (b) platinum, such that the amount of the oxygen contacted is 0.5 to 2 times the amount of the carbon monoxide contained in the hydrogen-containing gas.
A process for producing a hydrogen-containing gas for fuel cells, including reducing a concentration of carbon monoxide in the hydrogen-containing gas for fuel cells, comprising:
- (a) subjecting hydrocarbons or methanol to steam-reforming or partial oxidation to produce a hydrogen-containing gas, the hydrogen-containing gas including carbon monoxide;
- (b) contacting the carbon monoxide in said hydrogen-containing gas with oxygen at a temperature of 40 to 200° C. in the presence of a catalyst consisting of (1) at least one selected from the group consisting of cobalt, nickel, copper and manganese, and also (2) platinum, such that the amount of oxygen contacted is 0.5 to 2 times the amount of the carbon monoxide contained in the hydrogen-containing gas, thereby providing an oxygen-contacted, hydrogen-containing gas ;
- and
- (c) adapting the hydrogen-containing gas from (b) for use in fuel cells.
Dependencies are inferred from the claim text.