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US 6,547,834 B1Granted
Hair dye composition
AssigneeKao Corporation
InventorsKenichi Matsunaga, Hajime Miyabe, Yukihiro Ohashi, Shintaro Totoki, Yoshinori Saito
Life of this patent
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Abstract
A hair dye composition containing a direct dye (1) wherein, R1, R2 represents H or a lower alkyl group, A represents a group (2) or (3) and wherein B represents a group —Z1, —NR8—Z1 or —CH=Z2.
Claims20
A hair dye composition comprising, a direct dye compound of formula (1):
- wherein, R1 and R2 each independently represent a hydrogen atom or a C1-6 alkyl group which may have a substituent;
- A represents a group of formula (2):
- wherein R3, R4 and R5 each independently represent a C1-6 alkyl group which may have a substituent, or R4 and R5 may be coupled together to form a cyclic structure, benzene ring a1 may have a substituent other than a sulfonic acid group or may be condensed with an aromatic ring, or
- A is a group of formula (3):
- wherein W represents an aralkyl group, a carbamoylalkyl group or —T—NR6R7, wherein R6 and R7 each independently represent a C1-6 alkyl group which may have a substituent, an aromatic group which may have a substituent or a heterocyclic group which may have a substituent, or R6 and R7 may form a heterocyclic ring together with the adjacent nitrogen atom, and T represents a divalent linear C1-4 hydrocarbon group which may have a substituent, pyridine ring a2 may be condensed with an aromatic ring,
- B represents a group represented by the formula —Z1, —NR8—Z1 or —CH═Z2
- wherein when A is a group of formula (3) Z1 represents an aromatic or heterocyclic aromatic group which may have a substituent, R8 represents a hydrogen atom, a C1-4 alkyl group which may have a substituent or an aromatic group which may have a substituent or R8 and Z1 may be coupled together to form a nitrogen-containing heterocyclic group which may have a substituent, Z2 represents a divalent group obtained by removing two hydrogen atoms from the methylene group on the ring of a heterocyclic aromatic compound which may have a substituent,
- wherein when A is a group of formula (2) R8 represents a hydrogen atom, a C1-4 alkyl group which may have a substituent or an aromatic group which may have a substituent or R8 and Z1 may be coupled together to form a nitrogen-containing heterocyclic group which may have a substituent, Z2 represents a divalent group obtained by removing two hydrogen atoms from the methylene group on the ring of a heterocyclic aromatic compound which may have a substituent, and Z1 may have a substituent and is selected from the group consisting of
- with the proviso that when A is a group of formula (2), B represents the group —Z1 and Z1 represents an aromatic group or when A is a group of formula (2), B represents the group —CH═Z2, Z2 represents an indolinidene group and n does not stand for 0, the aromatic group or indolinidene group has at least one substituent represented by the formula:
- —NR9R10 wherein R9 represents a C1-4 alkyl group having as a substituent a chlorine atom or a cyano, an acylamino, an alkoxy, a monoalkylamino, a dialkylamino, a trimethylammoniumyl group, or a phenyl group which may have a substituent and R10 represents a C1-6 alkyl group which may have a substituent,
- n stands for an integer of 0 to 3, wherein when B represents the group —Z1 or group —NR8—Z1 n is 1 to 3 and when B represents the group —CH═Z2 n is 0 to 3;
- and
- Y31 stands for an anion.
10 more elements
A hair dye composition comprising, a direct dye compound selected from the group consisting of
A hair dye composition comprising, a direct dye compound selected from the group consisting of
Dependencies are inferred from the claim text.