Cellulose dispersion
AssigneeAsahi Kasei Kabushiki Kaisha
InventorsHirofumi Ono, Toshihiko Matsui, Ikuya Miyamoto
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AssigneeAsahi Kasei Kabushiki Kaisha
InventorsHirofumi Ono, Toshihiko Matsui, Ikuya Miyamoto
Estimating the term…
A cellulose dispersion which is a dispersion comprising a dispersing medium and a cellulose having a fraction of cellulose I type crystal component of not more than 0.1 and a fraction of cellulose II type crystal component of not more than 0.4 and in which the average particle diameter of the constitutive cellulose is not more than 5 μm. A cellulose particulate and a cellulose composite particulate which have an average particle diameter of 0.2 to 20 μm, a ratio of long diameter (L) to short diameter (D) observed through a scanning electron microscope (L/D) of not more than 1.2 and a coefficient of aggregation of 1.0 to 3.0. The present invention provides a cellulose dispersion which has an excellent effect such as dispersion stability or the like and is high in transparency. Moreover, it provides a cellulose particulate and a cellulose composite particulate which have such performances as no rough feel, excellent rolling properties, high dispersibility and the like.
A cellulose dispersion which is a dispersion comprising a dispersing medium and a cellulose having crystal forms of cellulose I and cellulose II, wherein a crystallinity of cellulose I is not more than 0.1 and a crystallinity of cellulose II is not more than 0.4 and wherein the average particle diameter of the cellulose in the dispersion is not more than 5 μm.
A process for producing a cellulose dispersion, which comprises dissolving a cellulose in an aqueous inorganic acid solution to prepare a cellulose solution, reprecipitating the cellulose solution in water or a coagulating agent containing not less than 50% by weight of water to prepare a cellulose suspension, subjecting the cellulose in the suspension to acid hydrolysis treatment, and subsequently removing the acid from the suspension.
A process for producing a cellulose dispersion, which comprises dissolving a cellulose in an aqueous inorganic acid solution to prepare a cellulose solution, reprecipitating the cellulose solution in water or a coagulating agent containing not less than 50% by weight of water to prepare a cellulose suspension, subsequently preparing a dehydrated cake of the cellulose from the suspension, thereafter introducing the dehydrated cake into water at not less than 50° C. to subject the cellulose to acid hydrolysis treatment and then removing the acid from the suspension.
A cellulose particulate which is composed of a cellulose having crystal forms of cellulose I and cellulose II, wherein a crystallinity of cellulose I is not more than 0.1 and a crystallinity of cellulose II is not more than 0.4, and which has an average particle diameter of 0.2 to 20 μm, a ratio of long diameter (L) to short diameter (D) as observed through a scanning electron microscope (L/D) of not more than 1.2 and a coefficient of aggregation of 1.0 to 3.0, provided that the coefficient of aggregation=(average particle diameter calculated from the volume reduced distribution obtained by a laser diffraction-scattering type particle size distribution measuring apparatus)/(average particle diameter of volume reduction by a scanning electron microscope).
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