Heavy oil upgrading process
AssigneeTrans Ionics Corporation
InventorRobert C. Schucker
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Abstract
An improved heavy oil conversion process is disclosed in which the heavy oil feed is first thermally cracked using visbreaking or hydrovisbreaking technology to produce a product that is lower in molecular weight and boiling point than the feed. The product is then deasphalted using an alkane solvent at a solvent to feed ratio of less than 2 wherein separation of solvent and deasphalted oil from the asphaltenes is achieved through the use of a two-stage membrane separation system in which the second stage is a centrifugal membrane.
Claims25
A process for the upgrading of a heavy oil feedstock that comprises the steps of thermally cracking said feedstock in a thermal cracking unit at conditions that will produce a thermally cracked product stream having a lower average molecular weight and boiling point than said feedstock without significant coke formation;
- volatilizing from said product stream light ends including any water that might be in the stream to form a devolatilized product stream;
- adding an alkane solvent to said devolitized product stream thereby inducing the formation of asphaltene aggregates and forming a devolatilized product/solvent mixture;
- passing said devolatilized product/solvent mixture to a first membrane permeation unit;
- recovering a permeate/solvent stream that is reduced in asphaltenes;
- heating said permeate/solvent above the solvent critical point;
- recovering said solvent and recycling it to a discharge of said thermal cracking unit;
- recovering a substantially deasphalted oil product;
- mixing a first retentate stream from said first membrane permeation unit, which is increased in asphaltenes, with a portion of the alkane solvent to form a first retentate/solvent mixture;
- passing said first retentate stream/solvent mixture to a second membrane permeation unit, to recover liquids that are associated with the asphaltenes in said first retentate/solvent mixture as a second permeate, which permeates through the second membrane;
- and
- recovering a high-solids retentate stream comprising predominantly asphaltenes, steam stripping said high-solids retentate and recovering the solids.
Dependencies are inferred from the claim text.