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US 6,485,875 B1Granted
Toner and resin composition for the toner
AssigneeCanon Kabushiki Kaisha
InventorsYuki Karaki, Hiroshi Yusa, Takashige Kasuya, Yoshihiro Ogawa
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Abstract
A toner is constituted by at least a binder resin, a colorant and a wax. The binder resin has been formed from monomers including a vinyl monomer and polyester-forming monomers containing at least a polybasic carboxylic acid having three or more carboxyl groups or its anhydride, and comprises at least a hybrid resin comprising a vinyl polymer unit and a polyester unit.
Claims42
A toner, comprising:
- at least a binder resin, a colorant and a wax, wherein
- the binder resin has been formed from monomers including a vinyl monomer and polyester-forming monomers containing at least a polybasic carboxylic acid having three or more carboxyl groups or its anhydride, and comprises at least a hybrid resin comprising a vinyl polymer unit and a polyester unit,
- the toner contains a THF (tetrahydrofuran)-soluble content which includes a first component having a molecular weights of below 1×104 containing W1 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the first component and a second component having a molecular weight of at least 1×104 containing W2 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the second component, W1 and W2 satisfying the following relationship:
- 0.1×W2<W2−W1<0.5×W2,
- 0≦W1<30,
- 0<W2<50, and
- W2>W1,
- the THF-soluble content provides a GPC (gel permeation chromatography) chromatogram including 40-70 wt. % (M1) of a component having molecular weights of below 1×104, 25-50 wt. % (M2) of a component having molecular weights of 1×104-5×104, 2-25 wt. % (M3) of a component having molecular weights of above 5×104, and below 10 wt. % (M4) of a component having molecular weights of at least 10×104, M1, M2 and M3 satisfying the following relationship:
- M1≧M2>M3.
6 more elements
A resin composition for a toner, comprising:
- at least a hybrid resin comprising a vinyl polymer unit and a polyester unit,
- wherein the resin composition has been formed from monomers including a vinyl monomer and polyester-forming monomers containing at least a polybasic carboxylic acid having three or more carboxyl groups or its anhydride,
- the resin composition contains a THF (tetrahydrofuran)-soluble content which includes a first component having molecular weights of below 1×104 containing w1 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the first component and a second component having molecular weight of at least 1×104 containing w2 (mol. %) of the polybasic carboxylic acid and its anhydride based on the polyester-forming monomers contained in the second component, w1 and w2 satisfying the following relationship:
- 0.1×w2<w2−w1<0.5×w2,
- 0≦w1<30,
- 0<w2<50, and
- w2>w1,
- the THF-soluble content provides a GPC (gel permeation chromatography) chromatogram including 40-75 wt. % (m1) of a component having molecular weights of below 1×104, 23-45 wt. % (m2) of a component having molecular weights of 1×104-5×104, 2-25 wt. % (m3) of a component having molecular weights of above 5×104, and below 13 wt. % (m4) of a component having molecular weights of at least 10×104, m1, m2, and m3 satisfying the following relationship:
- m1≧m2>m3.
6 more elements
Dependencies are inferred from the claim text.