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US 6,479,447 B2Granted
Bleaching composition for dry cleaning containing transition metal bleach catalyst
AssigneeUnilever Home & Personal Care USA, Division of Conopco, Inc.
InventorsDirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes J. Verhagen, Pieter van der Vlist
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Abstract
A bleaching composition is provided for effective bleaching with a bleach catalyst at low temperatures. The bleaching composition comprises of a) from 0.05 microM to 50 mM of an organic substance which forms a complex with a transition metal; b) a source of active oxygen corresponding to 0.05 to 100 mM of active oxygen; and c) an effective amount of liquid carbon dioxide.
Claims27
A bleaching composition comprising:
- a) from 0.05 microM to 50 mM of a complex comprising an organic substance which forms the complex with a transition metal, the complex having the general formula (A1):
- [MaLkXn]Ym (A1)
- in which:
- M represents a metal selected from Mn(II)-(III)-(IV)-(V), Cu(I)-(II)-(III), Fe(I)-(II)-(III)-(IV), Co(I)-(II)-(III), Ni(I)-(II)-(III), Cr(II)-(III)-(IV)-(V)-(VI)-(VII), Ti(II)-(III)-(IV), V(II)-(III)-(IV)-(V), Mo(II)-(III)-(IV)-(V)-(VI), W(IV)-(V)-(VI), Pd(II), Ru(II)-(III)-(IV)-(V) and Ag(I)-(II);
- L represents a ligand, or its protonated or deprotonated analogue;
- X represents a coordinating species selected from any mono, bi or tri charged anions and any neutral molecules able to coordinate the metal in a mono, bi or tridentate manner;
- Y represents any non-coordinated counter ion;
- a represents an integer from 1 to 10;
- k represents an integer from 1 to 10;
- n represents zero or an integer from 1 to 10;
- and
- m represents zero or an integer from 1 to 20, said complex having a log P of less than 3;
- b) a source of active oxygen corresponding to 0.05 to 100 mM (w/v) of active oxygen;
- and
- c) a dry cleaning effective amount of liquid carbon dioxide.
12 more elements
Dependencies are inferred from the claim text.