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US 6,476,237 B2Granted
Purification of alkylene carbonates
AssigneeHuntsman Petrochemical Corporation
InventorsJames R. Machac, Jr., Ralph M. DiGuilio, John R. Sanderson, Ronald L. Savage
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Abstract
Provided herein is a process for producing alkylene carbonates of ultra-high purity. According to the present invention, certain stages of traditional distillation of alkylene carbonate distillation are replaced by carbon treatment. Alkylene carbonates produced according to the invention have a color of less than 25 (Pt-Co), and are suitable for uses requiring ultra-pure alkylene carbonates.
Claims11
A process for providing a purified alkylene carbonate from a crude alkylene carbonate comprising the steps of:
- a) providing a crude alkylene carbonate by reacting carbon dioxide with an alkylene oxide in a reactor in the presence of a suitable catalyst;
- b) subjecting the crude alkylene carbonate to evaporation in a first evaporator to form a first evaporator overhead containing alkylene carbonate and a first evaporator bottoms stream containing the catalyst, and recycling the first evaporator bottoms stream to the reactor;
- c) subjecting the first evaporator overhead to evaporation in a second evaporator to form a second evaporator overhead containing light components present in the first evaporator overhead and recycling the light components to the reactor;
- and
- d) contacting the bottoms stream from the second evaporator with carbon to form a high purity alkylene carbonate product.
2 more elements
Dependencies are inferred from the claim text.