US 6,476,135 B1Granted

Polyolefin composition containing low viscosity propylene homopolymer, fiber and extensible non-woven fabric prepared therefrom

AssigneeBasell Poliolefine Italia S.r.l.

InventorsDaniele C. Bugada, Michael E. Starsinic

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Abstract

A polyolefin composition which contains 45 to 5 weight percent of a low viscosity propylene homopolymer having an as polymerized melt flow rate of 250 to 550 g/10 minutes and 55 to 95 weight percent of an olefin polymer composition, preferably a random copolymer of propylene and ethylene and/or a C4-10 alpha-olefin or mixtures thereof, containing from 90 to 99 weight percent propylene. The composition may be formed into fibers having a diameter of from 15 to 23 microns. The fibers may be used to produce nonwoven fabrics.

Claims7

Dependent claims

A polyolefin composition comprising:

A. 45 to 5 weight percent of a low viscosity propylene homopolymer having an as polymerized melt flow rate of from 250 to 550 g/10 minutes:
and
B. 55 to 95 weight percent of an olefin polymer composition selected from the group consisting of
(1) a random copolymer of propylene and ethylene and/or a C4-10 alpha-olefin, with the copolymer containing from 90 to 99 weight percent propylene;
(2) a propylene polymer composition consisting essentially of:
(a) from 30 to 65% of a copolymer of propylene with a C4-8 alpha-olefin, which contains from 80 to 98% propylene, and
(b) from about 35 to 70% of a copolymer of propylene with ethylene having an ethylene content of from 1 to 10% or a terpolymer of propylene with ethylene and a C4-8 alpha-olefin having a total comonomer content is from 2 to 10%;
(3) an olefin polymer composition consisting essentially of:
(a) from 10to 50% of a propylene homopolymer having an isotactic index of from 80 to greater than 99%, or a copolymer selected from the group consisting of (i) propylene and ethylene, (ii) propylene, ethylene and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, and (iii) propylene and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, wherein said copolymer contains from 85 to 99% propylene, and having an isotactic index greater than 80 to 98%,
(b) from 5 to 20% of a semi-crystalline, essentially linear copolymer fraction having a crystallinity of about 20 to 60%, by differential scanning calorimetry (DSC), wherein the copolymer is selected from the group-consisting of (i) ethylene and propylene containing over 55% ethylene;
(ii) ethylene, propylene, and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, containing from 1 to 10% of the alpha-olefin and over 55% up to 98% of both ethylene and alpha-olefin;
and (iii) ethylene and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, containing over 55% up to 98% of said alpha-olefin, which copolymer is insoluble in xylene at room or ambient temperature, and
(c) from 40 to 80% of a copolymer fraction selected from the group consisting of a copolymer of (i) ethylene and propylene wherein the copolymer contains from 20% to less than 40% ethylene;
(ii) ethylene, propylene, and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, wherein the alpha-olefin is present in an amount of from 1 to 10% and the amount of ethylene and alpha-olefin present is from 20% to less than 40%;
and (iii) ethylene and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, containing from 20 to less than 40% of the alpha-olefin, and optionally with 0.5 to 10% of a diene, said copolymer fraction being soluble in xylene at ambient temperature and having an intrinsic viscosity of from 1.7 to 3.0 dl/g, wherein the total amount of ethylene units or said alpha-olefin units in the olefin polymer composition, or of ethylene and said alpha-olefin units when both are present in the olefin polymer composition is from 15 to 35%, the total amount of (b) and (c) fractions, based on the total olefin polymer composition is from about 65% to 80%, the weight ratio of (b)/(c) is from 0.1 to about 0.3 and the total content of ethylene or C4-8 alpha-olefin or combination thereof in (b+c) is less than 50%;
(4) a thermoplastic olefin consisting essentially of:
(a) from 10 to 60% of a propylene homopolymer having an isotactic index greater than 90 or a crystalline propylene copolymer with ethylene and/or C4-8 alpha-olefin having a propylene content greater than 85% and an isotactic index of greater than 85%;
(b) from 30 to 60% of an amorphous ethylene-propylene copolymer fraction, optionally containing a minor amount of a diene, which is xylene soluble at room temperature, and contains from 40 to 70% ethylene;
(c) from 8 to 40% of a semi-crystalline ethylene-propylene copolymer which is xylene insoluble at room temperature;
and
(5) a linear low density polyethylene containing up to 20%, by weight, of a C4-8 α-olefin having a density of from 0.88 to 0.945 g/cm3 and a melt index of from 0.1 to 35 g/10 min;
(6) a high melt strength propylene polymer having a branching index of less than 0.9 or a melt tension of 3 to 28 cN;
and
(7) mixtures thereof.

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Dependencies are inferred from the claim text.

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Abstract

A polyolefin composition comprising:

A. 45 to 5 weight percent of a low viscosity propylene homopolymer having an as polymerized melt flow rate of from 250 to 550 g/10 minutes:
and
B. 55 to 95 weight percent of an olefin polymer composition selected from the group consisting of
(1) a random copolymer of propylene and ethylene and/or a C4-10 alpha-olefin, with the copolymer containing from 90 to 99 weight percent propylene;
(2) a propylene polymer composition consisting essentially of:
(a) from 30 to 65% of a copolymer of propylene with a C4-8 alpha-olefin, which contains from 80 to 98% propylene, and
(b) from about 35 to 70% of a copolymer of propylene with ethylene having an ethylene content of from 1 to 10% or a terpolymer of propylene with ethylene and a C4-8 alpha-olefin having a total comonomer content is from 2 to 10%;
(3) an olefin polymer composition consisting essentially of:
(a) from 10to 50% of a propylene homopolymer having an isotactic index of from 80 to greater than 99%, or a copolymer selected from the group consisting of (i) propylene and ethylene, (ii) propylene, ethylene and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, and (iii) propylene and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, wherein said copolymer contains from 85 to 99% propylene, and having an isotactic index greater than 80 to 98%,
(b) from 5 to 20% of a semi-crystalline, essentially linear copolymer fraction having a crystallinity of about 20 to 60%, by differential scanning calorimetry (DSC), wherein the copolymer is selected from the group-consisting of (i) ethylene and propylene containing over 55% ethylene;
(ii) ethylene, propylene, and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, containing from 1 to 10% of the alpha-olefin and over 55% up to 98% of both ethylene and alpha-olefin;
and (iii) ethylene and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, containing over 55% up to 98% of said alpha-olefin, which copolymer is insoluble in xylene at room or ambient temperature, and
(c) from 40 to 80% of a copolymer fraction selected from the group consisting of a copolymer of (i) ethylene and propylene wherein the copolymer contains from 20% to less than 40% ethylene;
(ii) ethylene, propylene, and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, wherein the alpha-olefin is present in an amount of from 1 to 10% and the amount of ethylene and alpha-olefin present is from 20% to less than 40%;
and (iii) ethylene and a CH2═CHR alpha-olefin, where R is a C2-8 straight or branched alkyl, containing from 20 to less than 40% of the alpha-olefin, and optionally with 0.5 to 10% of a diene, said copolymer fraction being soluble in xylene at ambient temperature and having an intrinsic viscosity of from 1.7 to 3.0 dl/g, wherein the total amount of ethylene units or said alpha-olefin units in the olefin polymer composition, or of ethylene and said alpha-olefin units when both are present in the olefin polymer composition is from 15 to 35%, the total amount of (b) and (c) fractions, based on the total olefin polymer composition is from about 65% to 80%, the weight ratio of (b)/(c) is from 0.1 to about 0.3 and the total content of ethylene or C4-8 alpha-olefin or combination thereof in (b+c) is less than 50%;
(4) a thermoplastic olefin consisting essentially of:
(a) from 10 to 60% of a propylene homopolymer having an isotactic index greater than 90 or a crystalline propylene copolymer with ethylene and/or C4-8 alpha-olefin having a propylene content greater than 85% and an isotactic index of greater than 85%;
(b) from 30 to 60% of an amorphous ethylene-propylene copolymer fraction, optionally containing a minor amount of a diene, which is xylene soluble at room temperature, and contains from 40 to 70% ethylene;
(c) from 8 to 40% of a semi-crystalline ethylene-propylene copolymer which is xylene insoluble at room temperature;
and
(5) a linear low density polyethylene containing up to 20%, by weight, of a C4-8 α-olefin having a density of from 0.88 to 0.945 g/cm3 and a melt index of from 0.1 to 35 g/10 min;
(6) a high melt strength propylene polymer having a branching index of less than 0.9 or a melt tension of 3 to 28 cN;
and
(7) mixtures thereof.

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