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US 6,475,376 B2Granted
Mild hydrotreating/extraction process for low sulfur fuel for use in fuel cells
AssigneeChevron U.S.A. Inc.
InventorsLawrence W. Jossens, Curtis L. Munson, Gunther H. Dieckmann
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Abstract
A two step sulfur removal for treatment of hydrocarbonaceous fuel intended for use in a fuel cell comprising a mild hydrotreating step followed by an extraction step reduces the sulfur content in fuel to 5 ppm total sulfur or less and a fuel processor suitable for carrying out the process.
Claims17
A process for desulfurizing a hydrocarbonaceous fuel intended for use in a PEM fuel cell which comprises:
- a) contacting a hydrocarbonaceous fuel containing sulfur with hydrogen in the presence of a hydrotreating catalyst at a temperature of between 300° F. and 500° F., a total pressure between 50 psig and 500 psig, and a space velocity between 0.5 hr−‘and 10 −1 for a time sufficient to convent up to 95% of the thiophenes present in the fuel, to produce a hydrotreated hydrocarbonaceous fuel;
- b) contacting the hydrotreated hydrocarbonaceous fuel with a solid adsorbent or a liquid extractant selected to reduce the sulfur compounds remaining in the hydrotreated hydrocarbonaceous to 5.0 ppm or less;
- c) recovering a hydrocarbonaceous fuel having a sufficiently reduced sulfur content wherein it is suitable for use as a fuel in a PEM fuel cell;
- and
- d) supplying the hydrocarbonaceous fuel recovered in step (c) as fuel for a PEM fuel cell.
2 more elements
Dependencies are inferred from the claim text.