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US 6,472,549 B1Granted
Process for the production of propyl silanes functionalized in 3-position
AssigneeDegussa AG
InventorsChristoph Batz-Sohn, Peter Panster, Rudolf Michel, Michael Albert, Ivo Vryens
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Abstract
Propyl silanes functionalized in 3-position are produced by catalytically reacting allyl compounds of the formula H2C═CH—CH2X with silanes of the formula R2R3R4SiH and using a 3- to 100-fold excess of silane.
Claims12
A process for the production of a 3-functionalized propyl silane comprising:
- adding an allyl compound of formula I
- H2C═CH—CH2X (I),
- wherein X is Cl, Br, I, F, CN, SCN, SH, SR, OH, NRR1 or OR and R and R1, both independently of each other, mean (C1-C6)alkyl or (C3-C7)alkyl,
- to a silanes of formula II
- R2R3R4SiH (II)
- wherein R2, R3, R4, all independently of each other, are hydrogen, halogen, (C1-C6)alkyl, (C1-C6)haloalkyl, (C3-C6)allyl, (C1-C4)alkoxy, phenyl, aryl or aralkyl,
- at a reaction temperature of 0° C. to 200° C. and a pressure of 800 mbar to 25 bar and in the presence of a platinum catalyst,
- wherein the silane (II) is brought into contact with the catalyst in a 3- to 100-fold molar excess in relation to the compound (I) to form an addition reaction.
5 more elements
Dependencies are inferred from the claim text.