Amines useful in inhibiting gas hydrate formation
AssigneeGoldschmidt Chemical Corporation
InventorsCharles R. Milburn, Gary M. Sitz
Life of this patent
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AssigneeGoldschmidt Chemical Corporation
InventorsCharles R. Milburn, Gary M. Sitz
Estimating the term…
A novel amine is provided with improved water dispersibility which is useful to modify the formation of hydrates in streams containing low-boiling hydrocarbons and water. The amine-has the formula: (RA—O—BT—Q)s—N+(C—C—CN+REkRD)xHv(RB)y(RC)p(RD)zAw wherein RA is selected from the group consisting of alkyl, alkenyl, aryl, arylalkyl, arylalkenyl, alkylaryl, and alkenylaryl groups and glycols having from 1 to 24 carbon atoms and optionally contains at least one hetero atom; Q is ethylene, propylene or butylene which may be linear or branched; x is 0 to 4; y and z are each independently 0 to x+1; w is 1 to x+1; v is a number which saturates the nitrogen atom; k and p are independently 0 or 1, with the proviso that k+p is greater than or equal to 1; s is 1, 2 or 3, preferably 1 or 2; T is from 0 to 20; each RE, RB and RC is independently selected from the group consisting of straight and branched chain alkyl groups containing 2 to 6 carbon atoms which may optionally be substituted with phenyl, and RE can be further (RA—O—BT—Q); each RD is independently selected from the group consisting of hydrogen and straight and branched chain alkyl groups containing 1 to 6 carbon atoms which may optionally be substituted with phenyl; B is a residual of ethylene oxide, propylene oxide or butylene oxide; and A is an anion.
A compound of formula (1)
A method for reducing the agglomerization of hydrates of hydrocarbons containing 1 to 5 carbon atoms, or decaying the formation of said hydrates comprising adding thereto an effective amount of at least one compound having the formula:
Dependencies are inferred from the claim text.