Process for producing semiconductor thin film devices using group 14 element and high temperature oxidizing treatment to achieve a crystalline silicon film
AssigneeSemiconductor Energy Laboratory Co., Ltd.
InventorsShunpei Yamazaki, Hisashi Ohtani
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Abstract
Under the conditions in that a germanium film 103 is formed on an amorphous silicon film 102, a first heat treatment (crystallization step) at from 450 to 600° C. is conducted. A second heat treatment is conducted for the resulting polysilicon film 104 at a temperature (from 800 to 1,050° C.) higher than the crystallization temperature. Through these steps, the boundary between the underlayer and silicon is fixed, to obtain a polysilicon film 105 containing substantially no defect in its crystal grain.
Claims21
A process for producing a semiconductor device comprising:
- forming a semiconductor film comprising silicon over a substrate,
- forming a thin film comprising an element selected from the group 14 on said semiconductor film,
- crystallizing said semiconductor film by a first heat treatment, to convert into a crystalline semiconductor film, and
- conducting a second heat treatment to said crystalline semiconductor film in an oxidizing atmosphere,
- said second heat treatment being conducted within a temperature range of 800 to 1050° C., which is higher than said first heat treatment.
A process for producing a semiconductor device comprising:
- forming a semiconductor film comprising silicon over a substrate,
- forming an insulating film having an opening on said semiconductor film,
- forming a thin film comprising an element selected from the group 14 to cover said insulating film and said opening,
- crystallizing a part of said semiconductor film by a first heat treatment, to convert into a crystalline semiconductor film, and
- conducting a second heat treatment to said crystalline semiconductor film in an oxidizing atmosphere,
- said second heat treatment being conducted within a temperature range of 800 to 1050° C., which is higher than said first heat treatment.
A process for producing a semiconductor device comprising:
- forming a semiconductor film comprising silicon over a substrate,
- forming an insulating film having an opening on said semiconductor film,
- adding an element selected from the group 14 to an exposed part of said semiconductor film through said opening,
- crystallizing a part of said semiconductor film by a first heat treatment, to convert into a crystalline semiconductor film, and
- conducting a second heat treatment to said crystalline semiconductor film in an oxidizing atmosphere,
- said second heat treatment being conducted within a temperature range of 800 to 1050° C., which is higher than said first heat treatment.
A process for producing a semiconductor device comprising:
- forming a semiconductor film comprising silicon over a substrate,
- coating a solution containing an element selected from the group 14, followed by spin drying, to form a layer containing said element selected from the group 14 on said semiconductor film,
- crystallizing said semiconductor film by a first heat treatment, to convert into a crystalline semiconductor film, and
- conducting a second heat treatment to said crystalline semiconductor film in an oxidizing atmosphere,
- said second heat treatment being conducted within a temperature range of 800 to 1050° C., which is higher than said first heat treatment.
A process for producing a semiconductor device comprising:
- forming a semiconductor film comprising silicon over a substrate,
- forming an insulating film having an opening on said semiconductor film,
- coating a solution containing an element selected from the group 14, followed by spin drying, to form a layer containing said element selected from the group 14 on an exposed part of said semiconductor film through said opening,
- crystallizing a part of said semiconductor film by a first heat treatment, to convert into a crystalline semiconductor film, and
- conducting a second heat treatment to said crystalline semiconductor film in an oxidizing atmosphere,
- said second heat treatment being conducted within a temperature range of 800 to 1050° C., which is higher than said first heat treatment.
A process for producing a semiconductor device comprising:
- forming a semiconductor film comprising silicon over a substrate, forming a thin film comprising an element selected from the group 14 on said semiconductor film,
- crystallizing said semiconductor film by a first heat treatment, to convert into a crystalline semiconductor film, and
- conducting a second heat treatment to said crystalline semiconductor film in an oxidizing atmosphere,
- said first heat treatment being conducted at a temperature of from 450 to 600° C., and said second heat treatment being conducted at a temperature of from 800 to 1,050° C.
A process for producing a semiconductor device comprising:
- forming a semiconductor film comprising silicon over a substrate,
- forming an insulating film having an opening on said semiconductor film,
- forming a thin film comprising an element selected from the group 14 to cover said insulating film and said opening,
- crystallizing a part of said semiconductor film by a first heat treatment, to convert into a crystalline semiconductor film, and
- conducting a second heat treatment to said crystalline semiconductor film in an oxidizing atmosphere,
- said first heat treatment being conducted at a temperature of from 450 to 600° C., and said second heat treatment being conducted at a temperature of from 800 to 1,050° C.
A process for producing a semiconductor device comprising:
- forming a semiconductor film comprising silicon over a substrate;
- coating a solution containing an element selected from the group 14, followed by spin drying, to form a layer containing said element selected from the group 14 on said semiconductor film,
- crystallizing a part of said semiconductor film by a first heat treatment, to convert into a crystalline semiconductor film, and
- conducting a second heat treatment to said crystalline semiconductor film in an oxidizing atmosphere,
- said first heat treatment being conducted at a temperature of from 450 to 600° C., and said second heat treatment being conducted at a temperature of from 800 to 1,050° C.
A process for producing a semiconductor device comprising:
- forming a semiconductor film comprising silicon over a substrate,
- forming an insulating film having an opening on said semiconductor film,
- coating a solution containing an element selected from the group 14, followed by spin drying, to form a layer containing said element selected from the group 14 on an exposed part of said semiconductor film through said opening,
- crystallizing a part of said semiconductor film by a first heat treatment, to convert into a crystalline semiconductor film, and
- conducting a second heat treatment to said crystalline semiconductor film in an oxidizing atmosphere,
- said first heat treatment being conducted at a temperature of from 450 to 600° C., said second heat treatment being conducted at a temperature of from 800 to 1,050° C.
Dependencies are inferred from the claim text.