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US 6,440,919 B1Granted
Aqueous based solvent free cleaner compositions containing two nonionic surfactants
AssigneeBASF SE
InventorsCharles O. Kerobo, Michael C. Welch, Suzanne M. Gessner, Sonia J. Patterson
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Abstract
The present invention relates to an aqueous based, solvent free degreaser composition, comprising a blend of two nonionic surfactants selected from, alcohol alkoxylate with a fatty alcohol moiety alkoxlyate, fatty alkoxlyated alcohol, fatty alcohol having oxyethylate moieties, polyoxyalkylene block copolymers, and alkyl phenol alkoxylate.
Claims1
An aqueous based solvent free degreaser composition comprising a nonionic surfactant component, wherein said nonionic surfactant component consists of two nonionic surfactants, wherein the first nonionic surfactant is:
- 0.15%-5% of an alcohol alkoxylate with a fatty alcohol moiety having the Formula:
- wherein R is a C8 to C18 branched or straight chain alkyl group;
- the sum of n plus o is from 4 to 12, the sum of m plus p is from 4 to 14;
- R′ is —CH3, —CH2CH3, or mixtures thereof;
- R″ is —CH3, —CH2CH3, or mixtures thereof;
- and R′″ is —OH, —OCH3, —O-C3-C18 hydroxyalkyl group;
- and the second nonionic surfactant is selected from the group consisting of:
- (1) 0.15%-5% of a nonionic surfactant characterized as a block or heteric/block polyoxyalkylene having a cloud point in a 1 weight percent aqueous solution of about 15° C. to about 25° C. having the Formula I:
- Y[(EO/A)m(A)nH]x (I)
- wherein Y represents the nucleus of an active hydrogen-containing organic compound having a functionality of x and (1) about 2 to about 6 carbon atoms and 2 to 3 reactive hydrogen atoms or (2) about 6 to about 18 carbon atoms and 1 to 3 reactive hydrogen atoms;
- A represents a lower alkylene oxide selected from the group consisting of propylene oxide, butylene oxide, tetrahydrofuran, and mixtures thereof wherein up to 25 percent by weight of A is reacted directly with said organic compound in admixture with ethylene oxide in Formula I and 75 percent by weight or more of A is subsequently reacted to produce said polymer;
- m is within the range of about 0 to 110, and n is within the range of about 0 to 26, wherein further, the molecular weight range is from about 1,000 to 20,000;
- (2) 0.15%-5% of a nonionic surfactant characterized as a block or heteric/block polyoxyalkylene having a cloud point in a 1 weight percent aqueous solution of about 15° C. to about 25° C. having the Formula II:
- Y[(A)o(EO)m(A)nH]x (II)
- wherein Y represents the nucleus of an active hydrogen-containing organic compound having a functionality of x and (1) about 2 to about 6 carbon atoms and 2 to 3 reactive hydrogen atoms or (2) about 6 to about 18 carbon atoms and 1 to 3 reactive hydrogen atoms;
- A represents a lower alkylene oxide selected from the group consisting of propylene oxide, butylene oxide, tetrahydrofuran, and mixtures thereof wherein up to 25 percent by weight of A is reacted directly with said organic compound alone in Formula II and 75 percent by weight of A is subsequently reacted to produce said polymer;
- o is within the range of about 0 to 26, m is within the range of about 0 to 110, and n is within the range of about 0 to 26, wherein further, the molecular weight range is from about 1,000 to 20,000;
- and
- (3) 0.15%-5% of a nonionic surfactant characterized as a block or heteric/block polyoxyalkylene having a cloud point in a 1 weight percent aqueous solution of about 15° C. to about 25° C. having the Formula III:
- Y[(A)o(EO/A)m(A)nH]x (III)
- wherein Y represents the nucleus of an active hydrogen-containing organic compound having a functionality of x and (1) about 2 to about 6 carbon atoms and 2 to 3 reactive hydrogen atoms or (2) about 6 to about 18 carbon atoms and 1 to 3 reactive hydrogen atoms;
- A represents a lower alkylene oxide selected from the group consisting of propylene oxide, butylene oxide, tetrahydrofuran, and mixtures thereof wherein up to 25 percent by weight of A is reacted directly with said organic compound alone in Formula III and 75 percent by weight or more of A is subsequently reacted to produce said polymer;
- o is within the range of about 0 to 26, m is within the range of about 0 to 110, and n is within the range of about 0 to 26, wherein further, the molecular weight range is from about 1,000 to 20,000.
20 more elements
Dependencies are inferred from the claim text.