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US 6,440,891 B1Granted
Catalyst comprising a complex of a metal of subgroup VIII, on the basis of a phosphonite ligand and method for hydroformylation
AssigneeBASF SE
InventorsHeiko Maas, Rocco Paciello, Michael Röper, Jakob Fischer, Wolfgang Siegel
Life of this patent
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Abstract
The catalyst comprises at least one bi- or more highly dentate phosphonite ligand of the general formula I or salts and mixtures thereof and is useful in a process for hydroformylating compounds containing at least one ethylenically unsaturated double bond by reaction with carbon monoxide and hydrogen.
Claims8
A catalyst comprising at least one rhodium complex with a phosphonite ligand of formula I
- wherein
- R1 is a C3-C6-chain wherein the carbon atoms are connected through single bonds or through single bonds and from 1 to 3 double bonds, which chain is optionally fused with from 1 to 3 rings selected from the group consisting of aryl and hetaryl, wherein the rings are unsubstituted or carry from 1 to 3 substituents selected from the group consisting of alkyl, cycloalkyl, aryl, alkoxy, cycloalkyloxy, aryloxy, halogen, trifluoromethyl, nitro, cyano, carboxyl and NE1E2,
- E1 and E2 are identical or different and each is alkyl, cycloalkyl or aryl,
- m is 0 or 1, and
- the moieties
- and
- are identical or different and denote each a 5- to 8-membered heterocycle which is optionally fused with from 1 to 3 rings selected from the group consisting of cycloalkyl, aryl and hetaryl, wherein the rings are unsubstituted or carry from 1 to 3 substituents selected from the group consisting of alkyl, alkoxy, halogen, nitro, cyano and carboxyl,
- or a salt thereof.
5 more elements
Dependencies are inferred from the claim text.