Unsymmetrical dioxazine compound dichroic dye liquid crystal composition and liquid crystal display element
AssigneesSumitomo Chemical Company, Limited, Japan as represented by Secretary of Agency of Industrial Science and Technology, New Energy and Industrial Technology Development Organization
InventorsToshihiko Tanaka, Toru Ashida
Life of this patent
Estimating the term…
Abstract
An unsymmetrical dioxazine compound represented by the formula (1-1) or (1-2) below, a dichroic dye, a liquid crystal composition containing the same, and a liquid crystal display element fabricated with the same: (In the formula, each of Y1 to Y3 stands for a group represented by the formula (2) or (3) ; X stands for H or the like; h is an integer of 0 to 2; A stands for phenylene or the like; E stands for phenylene or the like; G stands for H, F, or the like; i is an integer of 1 to 2; j is an integer of 0 to 2, each of J and M stands for phenylene or the like; and Q stands for H, F or the like.)
Claims5
An unsymmetrical dioxazine compound represented by the formula (1-1) or (1-2):
- wherein each of Y1 to Y3 stands for a group represented by the formula (2) or (3) with at least one of Y1 to Y3 being a group represented by the formula (2);
- X stands for a hydrogen atom, a halogen atom, a cyano group, an alkyl group, an aryl group, an alkoxy group, an acylamino group, or a carboxylate group:
- wherein h is an integer of 0 to 2, i is an integer of 1 to 2, and j is an integer of 0 to 2;
- A stands for a group selected from group (I) consisting of:
- wherein k is an integer of 1 to 6;
- one or more of hydrogen atoms in a phenylene group may be substituted by an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 12 carbon atoms, a perfluoroalkyl group having 1 to 6 carbon atoms, or a halogen atom;
- when said A is a group having ends (a) and (b), the end (a) binds to E or G and the end (b) binds to an ester group in the formula (2);
- each of E, J, and M stands for a group selected from group (I) consisting of:
- wherein m is an integer of 1 to 12, and each of q and r is an integer of 1 to 8;
- one or more of hydrogen atoms in a phenylene group may be substituted by an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6carbon atoms, a perfluoroalkyl group having 1 to 6 carbon atoms, or a halogen atom;
- when E in the formula (2) is a group having ends (a) and (b) , the end (a) binds to G or E and the end (b) binds to A or E;
- when J in the formula (3) is a group having ends (a) and (b) , the end (a) binds to M, J, or Q, and the end (b) binds to J or the triphenodioxazine skeleton;
- when M in the formula (3) is a group having ends (a) and (b), the end (a) binds to M or Q and the end (b) binds to M or J;
- G and Q each stands for a group selected from group (III) consisting of:
- wherein n is an integer of 1 to 12, and each of q, r, and s is an integer of 1 to 8.
An unsymmetrical dioxazine compound represented by one of the following formulae:
Dependencies are inferred from the claim text.