Formulations containing a phosphide for use in the controlled generation of phosphine

Abstract

A formulation for use in the controlled generation of phosphine comprises a mixture of a particulate phosphide and a water-immiscible compound. The water-immiscible compound is paraffin oil, petroleum jelly, a mixture of these materials or a wax having a melting point in the range 35° C. to 65° C. The phosphide comprises from 65 to 85 per cent (by weight) of the formulation. Such a formulation can be added progressively to water in a reaction chamber. Alternatively, the formulation can be packaged in a water-impermeable container from which a region can be removed to expose the formulation to water vapor in a gas flowing past the container. The water or the water vapor reacts with the phosphide particles as they become exposed to form phosphine. The phosphine, mixed with a carrier (usually air), may be fed into a duct connected to a grain silo, for fumigation of grain stored in the silo.

Dependencies are inferred from the claim text.