Curable epoxy resin compositions
AssigneeVantico Inc.
InventorsRolf Wiesendanger, Walter Fischer
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AssigneeVantico Inc.
InventorsRolf Wiesendanger, Walter Fischer
Estimating the term…
Curable epoxy resin compositions, which are obtainable by heating a composition containing at least one epoxy compound, which contains on average at least one, preferably more than one, 1,2-epoxy group and optionally also one or several hydroxyl groups in the molecule, in the presence of at least one Lewis acid as catalyst, wherein the Lewis acid is a salt of trifluoromethanesulfonic acid or of perchloric acid, the counterion of which carries a 2- to 6-fold positive charge, until the epoxy value, measured in equivalent epoxy/kg (Eq/kg) of the starting material, has been reduced by 1 to 60 percent, preferably by 5 to 50 percent; a process for their preparation, and their use for the preparation of fully cured moulded compositions or coatings. Claimed are, inter alia, also high molecular weight epoxy compounds of formula (IIa) wherein A is a divalent aliphatic or aromatic radical, B is the radical of the dioxan, which is substituted either in 2- and 5-position or in 2- and 6-position and which may be in the cis- or trans-form, and n is an integer from 1 to 10, preferably from 1 to 5.
A curable epoxy resin composition, which is obtainable by heating a composition free of non-aminic hardeners and containing at least one epoxy compound, which contains on average at least one 1,2-epoxy group and optionally also one or several hydroxyl groups in the molecule, in the presence of at least one Lewis acid as catalyst, wherein the Lewis acid is a salt of trifluoromethanesulfonic acid or of perchloric acid, the counterion of which carries a 2- to 6-fold positive charge, until the epoxy content, measured in equivalent epoxy/kg (Eq/kg) of the starting material, has been reduced by 1 to 60 percent.
A curable epoxy resin composition, which is obtainable by heating a composition essentially free of non-aminic hardeners and containing at least one epoxy compound, which contains on average at least one 1,2-epoxy group and optionally also one or several hydroxyl groups in the molecule, in the presence of at least one Lewis acid as catalyst, wherein the Lewis acid is a salt of trifluoromethanesulfonic acid or of perchloric acid, the counterion of which carries a 2- to 6-fold positive charge, until the epoxy content, measured in equivalent epoxy/kg (Eq/kg) of the starting material, has been reduced by 1 to 60 percent, wherein the epoxy compound is an aliphatic 1,4-bis(hydroxymethyl)cyclohexane diglycidyl ether, a hydrogenated diglycidyl ether of bisphenol A, 1,4-butanediol diglycidyl ether, 1,6- butanediol diglycidyl ether and/or a bis(hydroxymethyl)tricyclodecane diglycidyl ether.
A curable epoxy resin composition, which is obtainable by heating a composition essentially free of non-aminic hardeners and containing at least one epoxy compound, which contains on average at least one 1,2-epoxy group and optionally also one or several hydroxyl groups in the molecule, in the presence of at least one Lewis acid as catalyst, wherein the Lewis acid is a salt of trifluoromethanesulfonic acid or of perchloric acid, the counterion of which carries a 2- to 6-fold positive charge, until the epoxy content, measured in equivalent epoxy/kg (Eg/kg) of the starting material, has been reduced by 1 to 60 percent, wherein the epoxy compound contains on average one to two epoxy groups and one or several hydroxyl group in the molecule.
A divided package having at least a first part and a second part, wherein the first part contains a curable epoxy resin composition and the second part contains a suitable hardener, wherein the curable epoxy resin composition is obtainable by heating a composition essentially free of non-aminic hardeners and containing at least one epoxy compound, which contains on average at least one 1,2- epoxy group and optionally also one or several hydroxyl groups in the molecule, in the presence of at least one Lewis acid as catalyst, wherein the Lewis acid is a salt of trifluoromethanesulfonic acid or of perchloric acid, the counterion of which carries a 2- to 6-fold positive charge, until the epoxy content, measured in equivalent epoxy/kg (Eg/kg) of the starting material, has been reduced by 1 to 60 percent.
A high molecular weight epoxy compound of formula (IIa)
Dependencies are inferred from the claim text.