US 6,404,491 B1Granted

Rolling multiple internal reflection spectroscopy

AssigneeInternational Business Machines Corporation

InventorGareth Geoffrey Hougham

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Abstract

A structure is described having an optical element having a cylindrical shape adapted for rolling in contact with a surface of a material, a source of electromagnetic radiation coupled into one portion of the cylinder to interact with the surface, and exiting at another portion of the optical element for detection. An apparatus is described for applying electromagnetic radiation to a surface having a cylindrical roller formed from a material transmissive to the electromagnetic radiation; the cylindrical roller adapted for rolling on the surface; and the cylindrical roller adapted for receiving the electromagnetic radiation for reflecting the electromagnetic radiation therein and for directing the electromagnetic radiation towards a detector for detection. The structure and apparatus is directed for use with in-line or real-time process monitoring technology. More particularly to the problem of real-time spectroscopic determination of degree of chemical and physical changes to materials, in particular sheet materials, on a moving fabrication line. In many continuous-feed manufacturing processes involving sheet materials, monitoring the degree of chemical reaction and desiccation is essential and often problematic. Remote sensoring is often not possible due to the speed of material flow, or the necessity for sensor-element/sample contact. Many prior attempts to commercialize real-time monitoring systems have performed marginally or were useful under only a narrow range of circumstances.

An apparatus for applying electromagnetic radiation to a moving sheet of epoxy prepreg material to measure the extent of chemical cure of said moving sheet of epoxy prepreg material, said moving sheet of epoxy prepreg material having a top and bottom surface;

said apparatus comprising:
a feeder for feeding said moving sheet of epoxy prepreg material;
a collector for collecting said moving sheet of epoxy prepreg material;
an optical element, comprising a solid, cylindrical mechanically durable inner core roller having an exterior surface with a thin coating of transparent material secured thereon;
said optical element having a top and a bottom and two conical ends,
said thin coating of transparent material on said exterior surface of said inner core formed of a material selected from the group consisting of organic polymer or inorganic solids transmissive to said electromagnetic radiation, said electromagnetic radiation comprising the light wavelength ranges;
said optical element disposed between said feeder and said collector;
and
said optical element being adapted for rolling on said top surface of said moving sheet of epoxy prepreg material at a speed;
means for controlling the rotation speed of said optical element to synchronize said optical element speed with the speed of said moving sheet of epoxy prepreg material;
a plurality of alignment roller wheels arranged in staggered position forward and laterally with respect to one another and applying pressure against said top of said optical element so that said optical element contacts said moving sheet of epoxy prepreg material, said alignment rollers formed from an elastomer selected from the group consisting of siloxane and polyphosphazine:
a counterpressure roller contacting said bottom of said sheet of epoxy prepreg material so that there is the necessary physical contact between said sheet of epoxy prepreg material and said bottom of said optical element;
a circular coupling prism attached adjacent each said conical end of said optical element;
a source for directing said electromagnetic radiation into said thin coating of transparent material on said exterior surface of said inner core at an input location
at an angle below that for total internal reflection so that said electromagnetic radiation internally reflects within said thin coating of transparent material and determines the refractive index of said material using a critical angle technique wherein said radiation exits from said thin coating of transparent material on said exterior surface of said inner core cylinder at an output location;
a detector positioned to receive said electromagnetic radiation exiting said thin coating of transparent material on said exterior surface of said inner core,
said radiation detected by said detector providing the degree of chemical and physical changes of said epoxy prepreg material.

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Abstract

Claims3