Back to results
US 6,395,824 B1Granted
Aqueous dispersions containing polyurethanes with carbodiimide groups
AssigneeBASF SE
InventorsKuno Beutler, Karl Häberle, Rainer Hummerich, Ulrike Licht, Nicolas Kokel, Reinhard Treiber, Helmut Kaehs, Ralf Mossbach, Thomas Götz
Life of this patent
Estimating the term…
Abstract
Aqueous dispersions comprising a polyurethane which comprises carbodiimide structural units of the formula (I) —N═C═N— (I).
Claims11
An aqueous dispersion comprising a polyurethane (1), composed of
- a1) diisocyanates
- a1.1) which comprise structural units of the formula (I)
- —N═C═N— (I)
- and, optionally, those
- a1.2) which are free from structural units of the formula (I),
- b1) diols, of which
- b1.1) from 10 to 100 mol-%, based on the total amount of the diols (b1), have a molecular weight of from 500 to 5000 g/mol, and
- b1.2) from 0 to 90 mol-%, based on the total amount of the diols (b1), have a molecular weight of from 62 to 500 g/mol,
- c1) monomers which are chemically different from the monomers (a1) and (b1) and which have at least one isocyanate group or at least one isocyanate-reactive group and which, furthermore, carry at least one hydrophilic group or one potentially hydrophilic group, thereby rendering the polyurethanes dispersible in water,
- d1) optionally, further polyfunctional compounds which are different from the monomers (a1) to (c1) and which have reactive groups which are alcoholic hydroxyls, primary or secondary amino groups or isocyanate groups, and
- e1) optionally, monofunctional compounds which are different from the monomers (a1) to (d1) and which have a reactive group which is an alcoholic hydroxyl, a primary or secondary amino group or an isocyanate group.
8 more elements
An aqueous dispersion suitable for preparing coated textiles, comprising, based on the solids content,
- A) from 10 to 100% by weight of a polyurethane (1) which carries hydrophilic groups which render the polyurethane dispersible in water
- B) optionally, from 5 to 90% by weight of a polymer (B) which is
- B1) a polyurethane (2) different from the polyurethane (1) and composed of
- a2) diisocyanates containing no carbodiimide groups
- b2) diols, of which
- b2.1) from 10 to 100 mol-%, based on the total amount of the diols (b1), have a molecular weight from 500 to 5000 g/mol, and
- b2.2) from 0 to 90 mol-%, based on the total amount of the diols (b2), have a molecular weight of from 60 to 500 g/mol,
- c2) monomers which are chemically different from the monomers (a2) and (b2) and which have at least one isocyanate group or at least one isocyanate-reactive group and which, furthermore, carry at least one hydrophilic group or one potentially hydrophilic group, thereby rendering the polyurethanes dispersible in water,
- d2) optionally, further polyfunctional compounds which are different from the monomers (a2) to (c1) and which have reactive groups which are alcoholic hydroxyls, primary or secondary amino groups or isocyanate groups, and
- e2) optionally, monofunctional compounds which are different from the monomers (a2) to (d2) and which have a reactive group which is an alcoholic hydroxyl, a primary or secondary amino group or an isocyanate group,
- or
- B2) is a polymer prepared by free-radically initiated polymerization (polymer 3) which is composed of
- a3) from 30 to 100 parts by weight of at least one monomer selected from the group consisting of C1- to C20-alkyl(meth)acrylates, vinyl esters of carboxylic acids having up to 20 carbon atoms, ethylenically unsaturated nitrites, vinylaromatic compounds having up to 20 carbon atoms, vinyl halides, and aliphatic hydrocarbons having 2 to 8 carbon atoms and 1 or 2 double bonds (monomers a3), and
- b3) from 0 to 70 parts by weight of other compounds I having at least one ethylenically unsaturated group (monomers b3)
- C) optionally, from 0.1 to 5% by weight of an emulsifier
- D) optionally, from 0.1 to 10% by weight of an amino resin or phenolic resin
- E) optionally, from 1 to 30% by weight of a flame retardant
- F) optionally, from 1 to 70% by weight of a kaolin, and
- G) optionally, from 1 to 30% by weight of an oleophobicizer.
16 more elements
A method for architecturally preserving an object, comprising applying to said object a coated textile article as a roofing membrane or as a siding membrane.
Dependencies are inferred from the claim text.