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US 6,388,057 B1Granted
Crystalline modification of a water-insoluble monoazo dye
AssigneeDyStar Textilfarben GmbH & Co. Deutschland KG
InventorsToshio Hihara, Hiroshi Inoue, Yousuke Takahashi
Life of this patent
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Abstract
A water-insoluble monoazo dye represented by the following structural formula [I] having a crystal modification characterized by an X-ray diffraction pattern (CuKα) showing one strong peak at a diffraction angle (2θ) of 11.1±0.1° and also four intermediate peaks at 8.1±0.1°, 21.8±0.1°, 23.1±0.1° and 25.2±0.1°.
Claims4
A water-insoluble monoazo dye represented by the following structural formula [I]
- having a crystal modification characterized by an X-ray diffraction pattern (CuKα) showing one strong peak at a diffraction angle (2θ) of 11.1±0.1° and also four intermediate peaks at 8.1±0.1°, 21.8±0.1°, 23.1±0.1° and 25.2±0.1°.
A process to produce a water insoluble monoazo dye of the formula I
- having a crystal modification characterized by an X-ray diffraction pattern (CuKα) showing one strong peak at a diffraction angle (2θ) of 11.1±0.1° and also four intermediate peaks at 8.1±0.1°, 21.8±0.1°, 23.1±0.1° and 25.2±0.1°, which comprises synthesizing by diazotizing 6-chloro-2,4-dinitroaniline, and then carrying out a coupling reaction with 3-(N,N-diallyl)amino-4-methoxyacetanilide coupler in an aqueous medium at a temperature of 0 to 15° C. from 0.5 to 15 hours
- thereby forming the β-form and subjecting said β-form to further treatment which comprises
- 1)dispersing the β-form in an aqueous medium optionally in the presence of a dispersing agent then stirring at a temperature of 60 to 130° C. for 0.5 to 30 hours or
- 2)dispersing the β-form in an organic solvent and then stirring at a temperature of 15 to 100° C. for 0.5 to 10 hours.
1 more element
Dependencies are inferred from the claim text.