Method of preparing Rh- and/or Ru-catalyst supported on MgO carrier and reforming process using the catalyst

A method of preparing a catalyst, comprising the steps of:

• mixing magnesium oxide with a binder selected from the group consisting of carbon, fatty acids having 12-22 carbon atoms, magnesium salts of fatty acids having 12-22 carbon atoms, carboxymethyl cellulose, a magnesium salt of carboxymethyl cellulose, and polyvinyl alcohol to obtain a mixture in which said binder is present in an amount of 0.1-5% by weight based on the total weight of said mixture;
• molding said mixture;
• calcining said molded mixture at a temperature of at least 1,000° C. to obtain a carrier having a specific surface area of 5 m2/g of less;
• impregnating said carrier with an aqueous solution containing a catalytic metal component selected from the group consisting of rhodium compounds, ruthenium compounds and mixtures thereof so that the catalytic metal component is loaded on said carrier in an amount of 10-5,000 ppm, in terms of elemental metal, based on the weight of said carrier;
• drying and calcining said catalytic metal component-loaded carrier.