Process for producing hydrogen peroxide by direct synthesis
AssigneeDegussa-Huls AG
InventorsBirgit Bertsch-Frank, Ina Hemme, Lukas Von Hoppel, Stipan Katusic, Jürgen Rollmann
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Abstract
A process for the direct synthesis of hydrogen peroxide from hydrogen and oxygen is carried out in the presence of a noble metal catalyst. The selectivity for H2 and/or the maximum H2O2 concentration can be increased by using a catalyst of palladium or at least two metals selected from Group VIII and Group I of the Periodic Table of Elements, which catalyst has been produced by spray pyrolysis or flame pyrolysis.
Claims15
A process for producing hydrogen peroxide by direct synthesis comprising:
- converting hydrogen and oxygen to hydrogen peroxide in the presence of a heterogeneous catalyst containing at least one noble metal, as its catalytically active component, optionally in the presence of a solvent,
- wherein the catalytically active component comprises palladium or at least two metals selected from the group consisting of metals of Group VIII and Group I of the Periodic Table of Elements, which component has been produced by spray pyrolysis or flame pyrolysis, including the conversion of a solution or suspension, containing compounds of one or more catalytically active metals in a catalytically effective elemental ratio in dissolved form, into a gas-supported particle collective, introduction thereof into a spray pyrolysis or flame pyrolysis reactor, converting the compounds of the catalytically active metals into said metals or alloys thereof, and separating the solid particles formed from the gas stream.
A process for producing hydrogen peroxide by direct synthesis comprising:
- (a) providing a solution or a suspension containing compounds of one or more catalytically active metals in dissolved form, said metals comprising palladium or at least two metals selected from the group consisting of metals of Group VIII and Group I of the Periodic Table of Elements;
- (b) converting said solution or suspension into a gas-supported particle collective;
- (c) introducing said as-supported particle collective into a spray pyrolysis or flame pyrolysis reactor;
- (d) converting the compounds of the catalytically active metals into said metals or alloys thereof in said reactor;
- (e) separating the solid particles formed from the gas stream;
- (f) converting hydrogen and oxygen to hydrogen peroxide in the presence of a catalyst comprising said solid particles. optionally in the presence of a solvent.
Dependencies are inferred from the claim text.