Adsorbent compound for use in insulated glass windows
AssigneeUop LLC
InventorsThomas J. Dangieri, Nanette Greenlay
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AssigneeUop LLC
InventorsThomas J. Dangieri, Nanette Greenlay
Estimating the term…
In using partially alkali metal exchanged forms of FAU zeolite as selective adsorbents for use in insulated glass windows, particularly for use in a matrix in insulated glass windows, it has been discovered that significant reduction in the nitrogen loading on the zeolite results when the alkali metal content is maintained at a low level. For example, such FAU zeolites, particularly zeolite X which has been ion-exchanged with potassium ions to a level of between about 5 and about 75 equivalent mole percent indicate a nitrogen adsorption loading of between about 400 and 600 percent lower than unexchanged zeolite X and about 200 percent less than fully potassium exchanged zeolite X. The adsorbent is particularly useful in a sealant matrix for insulated glass windows and may be used in combination with zeolite A to reduce out-gassing problems.
A process for adsorbing solvent in a matrix for the fabrication of insulated glass windows having an enclosed space comprising a solvent, said process comprising adsorbing the solvent with an adsorbent compound comprising a zeolite A in combination with a FAU zeolite which has been partially ion-exchanged with a cation comprising an alkali metal, said faujasite having a framework silica-to-alumina ratio from 2.0 to 2.5 and containing from about 0.1 to about 75 equivalent mole percent of said cation.
A process for the adsorption of water and solvent vapor in insulated glass windows, said process comprising adsorbing the water and solvent with an adsorbent comprising a FAU zeolite having a framework silica to alumina ratio of from about 2.0 to 2.5 containing from about 5 to about 75 equivalent mole percent alkali metal cations selected from the group consisting of potassium, lithium, rubidium and cesium and having from 25 to about 95 mole percent sodium cations, the total cation equivalency contributed by the alkali metal cations and sodium being at least about 90 percent.
Dependencies are inferred from the claim text.