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US 6,387,136 B1Granted
Compositions for dyeing keratin fibers, containing 3-aminopyrazoline derivatives as coupler, dyeing process and dyeing kit
AssigneeL'oreal
InventorsPhilippe Breton, Alain Lagrange, Mireille Maubru
Life of this patent
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Abstract
Novel compositions for the oxidation dyeing of keratin fibers, comprising at least one oxidation base and at least one specific 3-aminopyrazoline as coupler, and dyeing process and dyeing kit using this composition.
Claims44
A composition for the oxidation dyeing of keratin fibers comprising:
- at least one oxidation base, and
- at least one coupler chosen from 3-amino-1-(4′-amino-3′-chlorophenyl)pyrazoline and 3-aminopyrazolines of formula (I) below and the acid addition salts thereof:
- wherein:
- R1 and R2, which may be identical or different, are each chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radicals;
- C1-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- and OR5 radicals,
- wherein R5 is chosen from C1-C4 alkyl radicals, aryl radicals, C1-C4 monohydroxyalkyl radicals, C2-C4 polyhydroxyalkyl radicals and (C1-C4)alkoxy(C1-C4)alkyl radicals;
- R3 and R4, which may be identical or different, are each chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radicals;
- C2-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- C1-C4 aminoalkyl radicals;
- (C1-C4)alkylamino(C1-C4)alkyl radicals;
- di((C1 -C4)alkyl)amino(C1-C4)alkyl radicals wherein said dialkyls may optionally form a 5- or 6-membered ring with the nitrogen atom to which they are bound, said ring optionally containing a heterocyclic atom in addition to the nitrogen atom;
- mono(hydroxy(C1-C4)alkyl)amino(C1-C4)alkyl radicals and di(hydroxy(C1-C4)alkyl)amino(C1-C4)alkyl radicals.
18 more elements
A process for dyeing keratin fibers, comprising
- separately storing a first composition,
- separately storing a second composition,
- thereafter mixing said first and second compositions,
- applying said mixture to said fibers, and
- developing for a period of time sufficient to achieve a desired coloration,
- wherein said first composition comprises
- at least one oxidation base, and
- at least one coupler chosen from 3-aminopyrazolines of formula (I) below and the acid addition salts thereof:
- in which:
- R1 and R2, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radials;
- C1-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- and OR5 radicals,
- in which R5 is chosen from C1-C4 alkyl radicals, aryl radicals, C1-C4 monohydroxyalkyl radicals, C2-C4 polyhydroxyalkyl radicals and (C1-C4)alkoxy(C1-C4)alkyl radicals;
- R3 and R4, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radicals;
- C2-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- C1-C4 aminoalkyl radicals;
- (C1-C4)alkylamino(C1-C4)alkyl radicals;
- di[(C1-C4)alkyl]amino(C1-C4)alkyl radicals;
- mono[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals and di[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals and
- wherein said second composition comprises an oxidizing agent.
25 more elements
A process for dyeing keratin fibers, comprising applying a composition for the oxidation dyeing of keratin fibers to said keratin fibers and developing for a period of time sufficient to achieve a desired coloration, wherein said composition comprises:
- at least one oxidation base, and
- at least one coupler chosen from 3-aminopyrazolines of formula (I) below and the acid addition salts thereof:
- in which:
- R1 and R2, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radials;
- C1-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- and OR5 radicals,
- in which R5 is chosen from C1-C4 alkyl radicals, aryl radicals, C1-C4 monohydroxyalkyl radicals, C2-C4 polyhydroxyalkyl radicals and (C1-C4)alkoxy(C1-C4)alkyl radicals;
- R3 and R4, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radicals;
- C2-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- C1-C4 aminoalkyl radicals;
- (C1-C4)alkylamino(C1-C4)alkyl radicals;
- di[(C1-C4)alkyl]amino(C1-C4)alkyl radicals;
- mono[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals and di[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals.
18 more elements
A multi-compartment dyeing kit, comprising at least two separate compartments, wherein a first compartment contains a first composition and a second compartment contains a second composition,
- wherein said first composition comprises
- at least one oxidation base, and
- at least one coupler chosen from 3-aminopyrazolines of formula (I) below and the acid addition salts thereof:
- in which:
- R1 and R2, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radials;
- C1-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- and OR5 radicals,
- in which R5 is chosen from C1-C4 alkyl radicals, aryl radicals, C1-C4 monohydroxyalkyl radicals, C2-C4 polyhydroxyalkyl radicals and (C1-C4)alkoxy(C1-C4)alkyl radicals;
- R3 and R4, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radicals;
- C2-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- C1-C4 aminoalkyl radicals;
- (C1-C4)alkylamino(C1-C4)alkyl radicals;
- di[(C1-C4)alkyl]amino(C1-C4)alkyl radicals;
- mono[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals and di[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals and
- wherein said second composition comprises an oxidizing composition.
20 more elements
A process for dyeing keratin fibers, comprising
- separately storing a first composition,
- separately storing a second composition,
- thereafter mixing said first and second compositions,
- applying said mixture to said fibers, and
- developing for a period of time sufficient to achieve a desired coloration,
- wherein said first composition comprises
- at least one oxidation base, and
- at least one coupler chosen from 3-amino-1-(4′-amino-3′-chlorophenyl)pyrazoline and 3-aminopyrazolines of formula (I) below and the acid addition salts thereof:
- in which:
- R1 and R2, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radials;
- C1-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- and OR5 radicals,
- in which R5 is chosen from C1-C4 alkyl radicals, aryl radicals, C1-C4 monohydroxyalkyl radicals, C2-C4 polyhydroxyalkyl radicals and (C1-C4)alkoxy(C1-C4)alkyl radicals;
- R3 and R4, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radicals;
- C2-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- C1-C4 aminoalkyl radicals;
- (C1-C4)alkylamino(C1-C4)alkyl radicals;
- di[(C1-C4)alkyl]amino(C1-C4)alkyl radicals;
- mono[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals and di[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals and
- wherein said second composition comprises an oxidizing composition containing at least one oxidizing agent.
25 more elements
A process for dyeing keratin fibers comprising,
- separately storing a first composition,
- separately storing a second composition,
- then sequentially applying said first composition and second compositions to said keratin fibers, and
- developing for a period of time sufficient to achieve a desired coloration,
- wherein said first composition comprises
- at least one oxidation base, and
- at least one coupler chosen from 3-amino-1-(4′-amino-3′-chlorophenyl)pyrazoline and 3-aminopyrazolines of formula (I) below and the acid addition salts thereof:
- in which:
- R1 and R2, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radicals;
- C1-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- and OR5 radicals,
- in which R5 is chosen from C1-C4 alkyl radicals, aryl radicals, C1-C4 monohydroxyalkyl radicals, C2-C4 polyhydroxyalkyl radicals and (C1-C4)alkoxy(C1-C4)alkyl radicals;
- R3 and R4, which may be identical or different, are chosen from a hydrogen atom;
- halogen atoms;
- C1-C4 alkyl radicals;
- C1-C4 monohydroxyalkyl radicals;
- C2-C4 polyhydroxyalkyl radicals;
- (C1-C4)alkoxy(C1-C4)alkyl radicals;
- C1-C4 aminoalkyl radicals;
- (C1-C4)alkylamino(C1-C4)alkyl radicals;
- di[(C1-C4)alkyl]amino(C1-C4)alkyl radicals;
- mono[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals and di[hydroxy(C1-C4)alkyl]amino(C1-C4)alkyl radicals and
- wherein said second composition comprises an oxidizing composition, wherein said oxidizing composition comprises at least one oxidizing agent.
24 more elements
Dependencies are inferred from the claim text.