Antistatic composition
Assignee3M Innovative Properties Company
InventorsWilliam M. Lamanna, Thomas P. Klun, Kathleen A. Hachey, Alan D. Fanta
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Abstract
An antistatic composition comprises (a) at least one ionic salt consisting of a nonpolymeric nitrogen onium cation and a weakly coordinating fluoroorganic anion, the conjugate acid of the anion being a superacid; and (b) at least one thermoplastic polymer. The composition exhibits good antistatic performance over a wide range of humidity levels.
Claims39
An antistatic composition comprising a melt blend of (a) at least one ionic salt consisting of a nonpolymeric nitrogen onium cation and a weakly coordinating fluoroorganic anion, the conjugate acid of said anion being a superacid;
- and (b) at least one thermoplastic polymer.
An antistatic composition comprising a melt blend of (a) at least one ionic salt consisting of (i) a nonpolymeric acyclic, saturated cyclic, or aromatic nitrogen onium cation and (ii) a weakly coordinating fluoroorganic anion, said aromatic nitrogen onium cation being selected from the group consisting of
- wherein R1, R2, R3, R4, and R5 are independently selected from the group consisting of H, F, alkyl groups of from 1 to about 4 carbon atoms, two said alkyl groups joined together to form a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N, and phenyl groups;
- and wherein said alkyl groups, said alkylene radicals, and said phenyl groups can be substituted with one or more electron withdrawing groups;
- and the conjugate acid of said anion being a superacid;
- and (b) at least one thermoplastic polymer.
An antistatic composition comprising a melt blend of (a) at least one ionic salt consisting of (i) a nonpolymeric nitrogen onium cation (1) selected from those represented by the formula
- (R1)4−zN+[(CH2)qOR2]z
- wherein each R1 is independently selected from the group consisting of alkyl, alicyclic, aryl, alkalicyclic, alkaryl, alicyclicalkyl, aralkyl, aralicyclic, and alicyclicaryl moieties that can contain one or more heteroatoms;
- each R2 is independently selected from the group consisting of hydrogen and the moieties described above for R1;
- z is an integer of 1 to 4;
- q is an integer of 1 to 4;
- or (2) selected from the group consisting of
- wherein R1, R2, R3, R4, R5, and R6 are independently selected from the group consisting of H, F, alkyl groups of from 1 to about 4 carbon atoms, two said alkyl groups joined together to form a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N, and phenyl groups;
- and wherein said alkyl groups, said alkylene radicals, and said phenyl groups can be substituted with one or more electron withdrawing groups;
- and (ii) a weakly coordinating fluoroorganic anion, the conjugate acid of which is a superacid, and that is selected from the group consisting of bis(perfluoroalkanesulfonyl)imides and tris(perfluoroalkanesulfonyl)methides;
- and (b) at least one thermoplastic polymer.
Trimethyl-3-perfluorooctylsulfonamidopropylammonium bis(trifluoromethanesulfonyl)imide.
A process for preparing an antistatic composition comprising the steps of (a) combining (i) at least one ionic salt consisting of a nonpolymeric nitrogen onium cation and a weakly coordinating fluoroorganic anion, the conjugate acid of said anion being a superacid, and (ii) at least one thermoplastic polymer;
- and (b) melt processing the resulting combination.
A topical treatment process comprising the step of applying a topical treatment composition to at least a portion of at least one surface of at least one insulating material, said topical treatment composition consisting essentially of at least one ionic salt consisting of (a) a nonpolymeric nitrogen onium cation selected from the group consisting of quaternary ammonium ions, tertiary ammonium ions, saturated cyclic nitrogen onium cations, and aromatic nitrogen onium cations;
- and (b) a weakly coordinating fluoroorganic anion;
- the conjugate acid of said anion being a superacid, and said ionic salt being a liquid at the application temperature.
Dependencies are inferred from the claim text.