Supported catalysts having a high sintering stability and a process for producing them

Abstract

Supported catalysts having a high sintering stability and comprising one or more noble metal cluster carbonyl compounds of the formula (1) [HaMbNcLd(CO)x]n−An+ and their use for the dehydrogenation, hydrogenation and oxidation of organic compounds where M and N are, independently of one another, one or more metals selected from the group consisting of Pt, Rh, Ir, Os, Ru, Ag, Pd, Au, Ni, Fe, Co, Cu, Re, Mn; L is one or more neutral or anionic ligands which may be identical or different; (A)n+ is one or more cations which balance the charge of the complex; a is an integer from 0 to 10, preferably from 0 to 6; b is an integer from 2 to 60; c is an integer from 0 to 30; d is an integer from 0 to 60; x is an integer from 1 to 120; n is the total charge of the complex which results from the individual charges of the constituents and is greater than 0, wherein the compounds of the formula (1) are located in the pores of a mesoporous support material.

Dependencies are inferred from the claim text.