Color-stable superabsorbent polymer composition
AssigneeBASF SE
InventorsPeter W. Carrico, David Eckert
Life of this patent
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Abstract
A color-stable superabsorbent polymer composition having long-term color stability, and methods of manufacturing the composition, are disclosed. The superabsorbent polymer composition contains an inorganic reducing agent and an optional metal salt, and resists color degradation during periods of extended storage, even at an elevated temperature and humidity.
Claims20
A color-stable superabsorbent polymer composition comprising (a) a superabsorbent polymer, said superabsorbent polymer comprising a polymerized α,β-unsaturated carboxylic acid or salt thereof, (b) about 0.5 to about 5 mole % of an inorganic reducing agent selected from the group consisting of a hypophosphite salt, a phosphite salt, and mixtures thereof, and (c) 0 to about 5 mole % of a water-soluble metal salt selected from the group consisting of an alkali metal salt, an alkaline earth metal salt, a metal salt having a polyvalent cation of valence II, III, or IV, and mixtures thereof, based on the amount of superabsorbent polymer in the composition.
A method of preventing discoloration of superabsorbent polymer particles comprising applying about 0.5 to about 5 mole % of an inorganic reducing agent selected from the group consisting of a hypophosphite salt, a phosphite salt, and mixtures thereof and 0 to about 5 mole % of a water-soluble metal salt selected from the group consisting of an alkali metal salt, an alkaline earth metal salt, a metal salt having a polyvalent cation of valence II, III, or IV, and mixtures thereof to a surface of the particles, to prevent an observable change in color of the particles after six months of storage at 60° C. and 75% humidity, wherein said superabsorbent polymer particles comprise a polymerized α,β-unsaturated carboxylic acid or salt thereof.
A color-stable superabsorbent polymer composition comprising (a) a superabsorbent polymer, (b) about 0.5 to about 5 mole % of an inorganic reducing agent selected from the group consisting of a hypophosphite salt, a phosphite salt, and mixtures thereof, and (c) 0 to about 5 mole % of a water-soluble metal salt selected from the group consisting of an alkali metal salt, an alkaline earth metal salt, a metal salt having a polyvalent cation of valence II, III, and IV, and mixtures thereof, based on the amount of superabsorbent polymer in the composition,
- said superabsorbent polymer selected from the group consisting of a poly(vinylamine), a poly(dialkylaminoalkyl (meth)acrylamide), a polyethylenimine, a poly(allylamine), a poly(allylguanidine), a poly(dimethyldiallylammonium hydroxide), a quaternized polystyrene derivative, a guanidine-modified polystyrene, a quaternized poly((meth)acrylamide), a poly(vinylguanidine), and salts and mixtures thereof.
Dependencies are inferred from the claim text.