Multifunction fractionation column for adsorptive separation processes

An adsorptive separation process which comprises:

• a.) passing a feed stream comprising a first and a second chemical compound into an adsorption zone comprising a bed of a selective adsorbent maintained at adsorption promoting conditions under which the first chemical compound is selectively retained on a quantity of the selective adsorbent, thus forming a raffinate stream comprising the second chemical compound and a desorbent compound formerly present in the quantity of the selective adsorbent;
• b.) passing a first desorbent stream comprising a desorbent compound into contact with said quantity of the selective adsorbent which has retained the first chemical compound under desorption promoting conditions to yield an extract stream comprising the desorbent compound and the first chemical compound;
• c.) passing the raffinate stream into an intermediate point of a first vertical fractionation zone of a fractionation column operated at fractionation conditions and divided into at least a first fractionation zone and a substantially parallel second fractionation zone, with each zone having an upper first end and a lower second end located within the fractionation column, with the first and second fractionation zones being in open communication at their lower ends, with the fractionation column also containing an undivided fractionation section extending downward from the point of open communication between the first and second fractionation zones, and with the column having a lower portion located below the first and second fractionation zones and divided by a vertical wall into a desorbent storage volume and a reboiler liquid volume;
• d.) passing the extract stream into an intermediate point of the second fractionation zone of the fractionation column;
• e.) recovering a raffinate product stream from an upper portion of the first fractionation zone;
• f.) recovering an extract product stream from an upper portion of the second fractionation zone, with the upper end of the second fractionation zone not being in communication with the first fractionation zone;
• g.) removing an second desorbent stream comprising the desorbent compound from the desorbent storage volume of the fractionation column, and passing the second desorbent stream into a liquid flow control device used to control the flow of desorbent into the adsorption zone.