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US 6,346,609 B1Granted
Cationic azo-dyes
AssigneeBASF SE
InventorsKarl-Heinz Etzbach, Torsten Freund, Rainer Tresch
Life of this patent
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Abstract
Cationic azo dyes of the general formula I where R1, R2, R3, A1, A2, B1, B2, An⊖, n and K have the meaning given in the specification are prepared and used for the dyeing and printing of natural or synthetic substrates and mixtures thereof.
Claims9
A cationic dye of formula I
- where
- R1 and R2 are independently hydrogen, nitro, halogen, C1-C6-alkyl,
- R3 is hydrogen, C1-C6-alkyl with or without interruption by 1 or 2 nonadjacent oxy, imino, C1-C6-alkylimino groups or by a
- radical,
- A1 and A2 are independently oxy, imino or substituted or unsubstituted C1-C6-alkylimino,
- B1 and B2 are independently C1-C6-alkylene with or without interruption by 1 or 2 nonadjacent oxy, imino, substituted or unsubstituted Cl1-6-alkylimino groups or by a
- radical,
- n is 1, and
- K is the radical of a coupling component or the radical of a monoazo dye of the formula
- where
- R4′ and R5′ are independently hydroxyl, amino, morpholino or mono- or di(C1-C6)alkylamino, whose alkyl radicals are unsubstituted or substituted by hydroxyl, amino, cyano, C1-C6-alkoxycarbonyl, carbamoyl or mono- or di(C1-C6)alkylcarbamoyl and uninterrupted or interrupted by oxy,
- Q1, Q2 and Q3 are independently hydrogen, C1-C10-alkyl with or without interruption by from 1 to 4 nonadjacent oxy, imino and substituted or unsubstituted C1-C4-alkylimino groups and with or without hydroxyl, halogen or phenyl substitution, or Q1 and Q2 combine with the linking nitrogen atom to form a 5- or 6-membered heterocyclic radical which optionally contains nitrogen or oxygen as further hetero atom, and
- An⊖ is the equivalent of an anion,
- and additionally n is from 2 to 8 when K is the radical of a coupling component of the formula IIIa′
- where
- R6′ is hydrogen, C1-C6-alkoxy with or without oxy interruption in its alkyl radical, mono- or di(C1-C6)alkylamino, C1-C6-alkoxycarbonyl, carbamoyl, mono- or di(C1-C6))alkylcarbamoyl, sulfamoyl, mono- or di(C1-C6)alkylsulfamoyl.
13 more elements
Dependencies are inferred from the claim text.