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US 6,333,423 B1Granted
Ultra-high activity non-metallocene pre-catalyst and method for catalytic polymerization of alpha-olefin monomers
AssigneesRamot University Authority for Applied Research and Industrial Development Ltd., Bar-Ilan University
InventorsMoshe Kol, Edit Tshuva, Zeev Goldschmidt
Life of this patent
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Abstract
Disclosed are compounds of the following formulae, and their use in the polymerization of olefins: wherein M is preferably titanium, zirconium or hafnium, R1-R8 are univalent radicals, X1 and X2 are univalent ligands, X3 is a divalent ligand, and (RnY—T) is an optional donor or non-donor group.
Claims36
A compound having a general structure selected from the group consisting of:
- wherein:
- a solid line represents a covalent bond;
- a dashed line represents a bond having a varying degree of covalency and a varying degree of coordination;
- M is a metal atom covalently bonded to each O atom and bonded with varying degrees of covalency and coordination to said N atom;
- X1 and X2 are each a univalent anionic ligand covalently bonded to said metal atom;
- X3 is a single divalent anionic ligand covalently bonded to said metal atom;
- R1 through R4 are each a univalent radical covalently bonded to first (C6) aromatic group;
- R5 through R8 are each a univalent radical covalently bonded to second (C6) aromatic group;
- and
- (RnY—T)is an optional group selected from the group consisting of a non-donor group covalently bonded to said N atom, wherein said non-donor group, T is a covalent bridging group between said N atom and Y, said Y is a group covalently bonded to said T, and, each of at least one Rn is selected from the group consisting of a saturated substituent covalently bonded to said Y, an unsaturated substituent covalently bonded to said Y, and a univalent radical covalently bonded to said Y, and a donor group covalently bonded to said N atom, wherein said donor group, T is a covalent bridging group between said N atom and Y, said Y is a heteroatom covalently bonded to said T and bonded with varying degrees of covalency and coordination to said metal atom, and, optional Rn substituents are selected from the group consisting of at least one saturated substituent covalently bonded to said Y, and at least one unsaturated substituent covalently bonded to said Y.
7 more elements
A compound of a general formula selected from the group consisting of:
- [{(O)1R1R2R3R4(C6)1(CH2)1(RnY—T)N(CH2)2(C6)2R5R6R7R8(O)2}MX1X2]
- and
- [{(O)1R1R2R3R4(C6)1(CH2)1(RnY—T)N(CH2)2(C6)2R5R6R7R8(O)2}MX3],
- wherein:
- M is a metal atom covalently bonded to each said (O)1 atom and bonded with varying degrees of covalency and coordination to said N atom;
- X1 and X2 are each a univalent anionic ligand covalently bonded to said metal atom;
- X3 is a single divalent anionic ligand covalently bonded to said metal atom;
- (C6)1 is a six carbon aromatic group covalently bonded to (O)1 and covalently bonded to (CH2)1;
- R1 through R4 are each a univalent radical covalently bonded to said (C6)1 group;
- (C6)2 is a six carbon aromatic group covalently bonded to (O)2 and covalently bonded to (CH2)2;
- R5 through R8 are each a univalent radical covalently bonded to said (C6)2 group;
- and
- (RnY—T) is an optional group selected from the group consisting of a non-donor group covalently bonded to said N atom, wherein said non-donor group, T is a covalent bridging group between said N atom and Y, said Y is a group covalently bonded to said T, and, each of at least one Rn is selected from the group consisting of a saturated substituent covalently bonded to said Y, an unsaturated substituent covalently bonded to said Y, and a univalent radical covalently bonded to said Y, and a donor group covalently bonded to said N atom, wherein said donor group, T is a covalent bridging group between said N atom and Y, said Y is a heteroatom covalently bonded to said T and bonded with varying degrees of covalency and coordination to said metal atom, and, optional Rn substituents are selected from the group consisting of at least one saturated substituent covalently bonded to said Y, and at least one unsaturated substituent covalently bonded to said Y.
10 more elements
Dependencies are inferred from the claim text.