Method and apparatus for separation of heavy and tritiated water
AssigneeThe United States of America as represented by the Department of Energy
InventorMyung W. Lee
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Abstract
The present invention is a bi-thermal membrane process for separating and recovering hydrogen isotopes from a fluid containing hydrogen isotopes, such as water and hydrogen gas. The process in accordance with the present invention provides counter-current cold and hot streams of the fluid separated with a thermally insulating and chemically transparent proton exchange membrane (PEM). The two streams exchange hydrogen isotopes through the membrane: the heavier isotopes migrate into the cold stream, while the lighter isotopes migrate into the hot stream. The heavy and light isotopes are continuously withdrawn from the cold and hot streams respectively.
Claims18
A method for separating and recovering hydrogen isotopes from a fluid containing hydrogen isotopes, said method comprising the steps of:
- (a) communicating a first stream of a fluid containing hydrogen isotopes at a first temperature in a first direction between a first end and a second end;
- (b) communicating a second stream of said fluid containing hydrogen isotopes at a second temperature lower than the first temperature in a second direction opposite to the first direction between said second end and said first end;
- (c) interposing a proton exchange membrane between the streams, said proton exchange membrane being made of thermally insulating and chemically transparent material that allows exchange of heavy and light hydrogen isotopes therethrough, wherein heavier isotopes migrate from the first stream to the second stream for thereby producing a deuterium and tritium-enriched fluid, while lighter isotopes migrate to the first stream from the second stream for thereby producing a lighter isotope-enriched fluid;
- (d) removing the deuterium and tritium-enriched fluid from the first end, and
- (e) removing the lighter isotope-enriched fluid from the second end.
An apparatus for separating and recovering hydrogen isotopes from a fluid containing hydrogen isotopes, said apparatus comprising:
- a container;
- a proton exchange membrane disposed within said container and dividing said container into a first chamber for containing a first stream of said fluid containing hydrogen isotopes at a first temperature and a second chamber containing a second stream of said fluid containing hydrogen isotopes at a second temperature, the first and second streams being interconnected at their respective ends for forming a continuous loop within said container;
- said proton exchange membrane being made of thermally insulating and chemically transparent material that allows exchange of heavy and light hydrogen isotopes therethrough, wherein heavier isotopes migrate from the first stream to the second stream for thereby producing a deuterium and tritium-enriched fluid, while lighter isotopes migrate to the first stream from the second stream for thereby producing a lighter isotope-enriched fluid.
Dependencies are inferred from the claim text.