Method of increasing the dry strength of paper products using cationic dispersion polymers
AssigneeNalco Chemical Company
InventorJordi Roqué Sanchez
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Abstract
This invention is directed to method for improving the dry strength of a paper product using a single cationic dispersion polymer strength additive, wherein the cationic dispersion polymer is prepared by polymerizing in an aqueous solution of a polyvalent anionic salt in the presence of a dispersant: i. a cationic diallyl-N,N-disubstituted ammonium halide monomer of formula (H2C═CHCH2)2N+R1R2X− wherein R1 and R2 are independently C1-C20 alkyl, aryl or arylalkyl and X is an anionic counterion and ii. an acrylamide monomer of formula wherein R3and R4 are independently hydrogen, C1-C10 alkyl, aryl or arylalkyl; R5 is hydrogen or methyl and R6 and R7 are independently hydrogen or C1-C10 alkyl.
Claims5
A method for improving the dry strength of a paper product comprising
- a) adding to an aqueous cellulosic papermaking slurry an effective amount of one or more retention and drainage aids and an effective amount of a sole polymeric strength additive, wherein the polymeric strength additive is a cationic dispersion polymer prepared by polymerizing in an aqueous solution of a polyvalent anionic salt in the presence of a dispersant of:
- i. a cationic diallyl-N,N-disubstituted ammonium halide monomer of formula
- (H2C═CHCH2)2N+R1R2X−
- wherein R1 and R2 are independently C1-C20 alkyl, aryl or arylalkyl and X is an anionic counterion and
- ii. an acrylamide monomer of formula
- wherein
- R3 and R4 are independently hydrogen, C1-C10 alkyl, aryl or arylalkyl;
- R5 is hydrogen or methyl and
- R6 and R7 are independently hydrogen or C1-C10 alkyl,
- wherein the cationic dispersion polymer has a reduced specific viscosity of from about 0.5 to about 8 deciliters per gram, measured in 1.0 N ammonium nitrate solution, and a cationic charge of from about 25 mole percent to about 50 mole percent;
- b) draining the slurry to form a sheet;
- and
- c) drying the sheet.
Dependencies are inferred from the claim text.