Multireactor parallel flow hydrocracking process
AssigneeUop LLC
InventorsTom N. Kalnes, Stephen R. Dunne, Vasant P. Thakkar
Life of this patent
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Abstract
Heavy hydrocarbons are upgraded to higher value distillates in a hydrocarbon conversion process which employs several parallel reaction zones which each contain both hydrotreating and hydrocracking catalyst beds. The feed and liquid recycle from the bottom of the reaction zone is charged to the top of the uppermost catalyst bed. Hydrogen flow is countercurrent to the descending liquid, and products are removed overhead through vapor-liquid contactors. The flow of feed to one of the reaction zones is periodically stopped to allow sequential on-stream hydrogenative regeneration of the catalysts within the reaction zone.
Claims15
A hydrocarbon conversion process which comprises:
- a.) dividing a feed stream into a number of portions having the same composition and passing each portion into an upper portion of a separate reaction zone of a multi-reaction zone reaction section of the process, with the reaction section comprising at least two reaction zones of substantially equal configuration and operated at substantially the same conversion conditions, and with each reaction zone containing a catalyst bed comprising hydrocracking catalyst;
- b.) passing a hydrogen-rich gas stream into a lower portion of each reaction zone and upward through the reaction zone;
- c.) collecting liquid phase hydrocarbons at the bottom of each reaction zone and recycling at least a portion of these hydrocarbons to a catalyst bed of the same reaction zone;
- and,
- d.) combining vapor rising out of each operating reaction zone and passing the resultant combined gas stream to a product recovery section of the process.
A hydrocarbon conversion process which comprises:
- a.) dividing a feed stream into a number of portions having the same composition and passing each portion into an upper portion of a separate reaction zone of a multi-reaction zone reaction section of the process, with the reaction section comprising at least two reaction zones of substantially equal configuration and operated at substantially the same conversion conditions, and with each reaction zone containing an upper first catalyst bed comprising hydrotreating catalyst and a lower second catalyst bed comprising hydrocracking catalyst;
- b.) passing a hydrogen-rich gas stream into a lower portion of each reaction zone and upward through the reaction zone;
- c.) collecting liquid phase hydrocarbons at the bottom of each reaction zone and recycling at least a portion of these hydrocarbons to the first catalyst bed of the same reaction zone;
- and,
- d.) combining vapor rising out of each operating reaction zone and passing the resultant combined gas stream to a product recovery section of the process.
A hydrocarbon conversion process which comprises:
- a.) dividing a feed stream into a number of portions having the same composition and passing each portion of the feed stream into a separate on-stream reaction zone of a reaction section comprising at least two on-stream reaction zones and at least one off-stream all of substantially equal configuration and operated at substantially the same pressure, with each reaction zone containing an upper first catalyst bed comprising hydrotreating catalyst and a lower second catalyst bed comprising hydrocracking catalyst;
- b.) passing a hydrogen-rich gas stream into a lower portion of each reaction zone and upward through the reaction zones including the regenerating reaction zone,
- c.) collecting liquid phase unconverted hydrocarbons at the bottom of each on-stream reaction zone and recycling at least a portion of the unconverted hydrocarbons to the first catalyst bed of the same on-stream reaction zone;
- d.) passing vapor rising out of the first catalyst bed upward through a vapor-liquid contacting zone located within the reaction zone;
- e.) combining vapor rising out of the vapor liquid contacting zone of the on-stream reaction zones and the regenerating reaction zone, and passing the resultant combined gas stream to a product recovery section of the process;
- and,
- f.) returning the off-stream reaction zone to on-stream operation and sequentially beginning regeneration of a different reaction zone to provide a continuous process.
A hydrocracking process which comprises:
- a.) dividing a feed stream into a number of portions having the same composition and passing each portion of the feed stream into the upper portion of a separate on-stream reaction zone of a reaction section comprising at least two on-stream reaction zones and at least one off-stream reaction zone which is being regenerated all of substantially equal configuration and operated at substantially the same pressure, with each reaction zone containing an upper first catalyst bed comprising hydrotreating catalyst and a lower second catalyst bed comprising hydrocracking catalyst,
- b.) passing a hydrogen-rich gas stream into a lower portion of each reaction zone, including the regenerating reaction zone, and upward through the reaction zone
- c.) collecting liquid phase unconverted hydrocarbons at the bottom of each on-stream reaction zone and recycling at least a portion of the unconverted hydrocarbons to the first catalyst bed of the same on-stream reaction zone, while retaining a pool of liquid phase hydrocarbons in the bottom of the on-stream reaction zones;
- d.) passing vapor rising out of the first catalyst bed of each reaction section upward through a contacting zone located within an upper portion of the reaction zone countercurrent to descending liquid phase hydrocarbons;
- e.) combining vapor rising out of the contacting zone of the on-stream reaction zones and the regenerating reaction zone, and passing the resultant combined gas stream to a product recovery section of the process;
- f.) returning the off-stream reaction zone to on-stream operation;
- g.) beginning regeneration of a different reaction zone, with all of the reaction zones being sequentially regenerated to provide a continuous process;
- and,
- h.) recovering a product distillate stream and a liquid hydrocarbon stream which is charged to the contacting zones from the combined gas stream.
Dependencies are inferred from the claim text.