Methacrylic acid ester resin composition and film made thereof
AssigneeKaneka Corporation
InventorsKeishi Koizumi, Shigemi Matsumoto, Takao Okimi, Juuichi Nishimura
Life of this patent
Estimating the term…
Loading patent…
AssigneeKaneka Corporation
InventorsKeishi Koizumi, Shigemi Matsumoto, Takao Okimi, Juuichi Nishimura
Estimating the term…
A methacrylate, resin composition having an excellent processability and capable of providing films having excellent impact resistance, transparency, weatherability, solvent resistance and plasticizer migration resistance, which comprises (A) 5 to 50% by weight of a crosslinked acrylate elastomer having a two layer structure of a crosslinked polymer component (a-1) having a glass transition temperature of −30 to 10° C. and a crosslinked polymer component (a-2) having a glass transition temperature of less than −30° C. wherein the component (a-1) is located on the inner side or the outer side and the component (a-2) is located on the outer side or the inner side, and (B) 95 to 50% by weight of an alkyl methacrylate polymer prepared by polymerizing an acrylic monomer containing 80 to 100% by weight of an alkyl methacrylate and 20 to 0% by weight of an alkyl acrylate in the presence of a chain transfer agent and in the presence or absence of the elastomer (A). The composition may further contain a core-shell polymer prepared by graft-polymerizing a monomer containing a major amount of an alkyl methacrylate onto a crosslinked acrylate polymer, whereby molded articles having a matt surface and an excellent flex whitening resistance are obtained.
A methacrylate resin composition comprising:
A thermoplastic resin composition comprising the methacrylate resin composition of claim 1 and 0.5 to 50 parts by weight, per 100 parts by weight of said methacrylate resin composition. of a core-shell polymer (C) prepared by graft-polymerizing (c-1) 60 to 15 parts by weight of a monomer component containing 60 to 100% by weight of an alkyl methacrylate, 0 to 40% by weight of an alkyl acrylate and 0 to 10% by weight of at least one other copolymerizable vinyl monomer onto (c-2) 40 to 85 parts by weight of a crosslinked acrylate polymer prepared by a polymerization of an acrylic monomer mixture of 40 to 90% by weight of an alkyl acrylate, 60 to 10% by weight of an alkyl methacrylate and 0 to 10% by weight of at least one other copolymerizable vinyl monomer and 0.1 to 20 parts by weight, per 100 parts by weight of said acrylic monomer mixture, of a polyfunctional monomer having at least two non-conjugated double bonds per molecule and copolymerizable with said acrylic monomer mixture, the total of said components (c-1) and (c-2) being 100 parts by weight.
Dependencies are inferred from the claim text.