Polyester laminate film, metal plate laminated with this film and film-laminated metal container
AssigneeToyo Boseki Kabushiki Kaisha
InventorsHideki Shimizu, Hiroshi Nagano, Tsutomu Oko, Hideki Igushi
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AssigneeToyo Boseki Kabushiki Kaisha
InventorsHideki Shimizu, Hiroshi Nagano, Tsutomu Oko, Hideki Igushi
Estimating the term…
A polyester laminate film comprising plural polyester layers, which comprises one surface layer comprising a polyester and a lubricant having an average particle size of 1-3 μm in a proportion of 1-5 wt % and the other surface layer comprising a polyester wherein 5-15 mol % of the entire acid component is a dimer acid component, the polyester laminate film having a crystallization peak temperature of 80-120° C. under temperature rise of the On The polyester laminate film of the present invention has a lower crystallization peak temperature when the film is under temperature rise, as compared to conventional polyethylene terephthalate. As a consequence, the film is free of whitening upon retorting, even after the film was subjected to remelting treatment and rapid cooling for noncystallization and unorienting. Therefore, the film serves well as a laminate film for food containers and beverage cans that undergo retort sterilization. Inasmuch as the polyester layer on one surface contains a large amount of a lubricant and has releasing property, the film serves well as a laminate film for a metal plate, which is required to have releasing property from a mold during manufacture of containers such as a two-piece can. The polyester layer on the other surface contains a large amount of dimer acid and the film is superior in impact resistance. Hence, the film serves well as a laminate film for a metal container which is susceptible to damage due to impact during distribution process.
A polyester laminate film comprising plural polyester layers, which comprises one polyester surface layer having a melting peak temperature of 200-260° C. and a crystallization peak temperature of 60-100° C. under temperature rise of the layer, and the other polyester surface layer having a melting peak temperature of 180-240° C. and a crystallization peak temperature of 60-100° C. under temperature rise of the layer, wherein the melting peak temperature of said one polyester surface layer is higher by 5-25° C. than the melting peak temperature of said other polyester surface layer.
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