Compostable adhesive
AssigneesBayer Aktiengesellschaft, Biotec Biologische
InventorsErnst Grigat, Karsten-Josef Idel, Uwe Westeppe, Wolfgang Schulz-Schlitte, Winfried Pommeranz, Jürgen Lörcks, Harald Schmidt
Life of this patent
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Abstract
The present invention relates to a compostable adhesive, to a method of producing the same, and to the use of the adhesive for the adhesive bonding of materials.
Claims11
A compostable adhesive comprising a solution of 1 to 70% by weight, with respect to the polymer constituent, of biodegradable polymers selected from the group consisting of thermoplastic aliphatic or partially aromatic polyester urethanes, aliphatic or aliphatic-aromatic polyester carbonates and aliphatic or partially aromatic polyester amides, wherein
- a) the aliphatic or partially aromatic polyester urethanes are prepared by reacting an ester component prepared from starting materials selected from the group consisting of:
- A) alcohol components selected from the group consisting of aliphatic bifunctional alcohols;
- cycloaliphatic bifunctional alcohols;
- monomeric or oligomeric polyols based on ethylene glycol, propylene glycol, tetrahydrofuran or copolymers thereof with molecular weights up to 4000 daltons and mixtures thereof;
- and optional small amounts of components selected from the group consisting of branched bifunctional alcohols, higher-functional alcohols and mixtures thereof;
- and
- acid components selected from the group consisting of aliphatic bifunctional acids, aromatic bifunctional acids and mixtures thereof;
- and optional small amounts of higher-functional acids;
- B) from units functionalized by both acid and alcohol, their derivatives and mixtures thereof;
- and
- combinations of A and B selected from the group consisting of a mixture, a copolymer and a mixture thereof,
- wherein the aromatic acids make up not more that 50 wt. % of all acids;
- with
- C) functional monomers selected from the group consisting of aliphatic bifunctional isocyanates, cycloaliphatic bifunctional isocyanates, and mixtures thereof,
- optional higher-functional isocyanates;
- optional linear, branched or cycloaliphatic bifunctional alcohols;
- linear, branched or cycloaliphatic higher functional alcohols;
- and mixtures thereof;
- optional linear, branched or cycloaliphatic bifunctional amines;
- linear, branched or cycloaliphatic higher functional amines and mixtures thereof,
- optional amino alcohols, higher functional amino alcohols and mixtures thereof;
- and
- optional other modified amines or alcohols,
- wherein the ester component is at least 75 wt. % of the sum of the ester component and C;
- b) aliphatic or aliphatic-aromatic polyester carbonates prepared by reacting as starting material, an ester or a mixture thereof as described in (a) with
- D) a carbonate fraction selected from the group consisting of 1) aromatic bifunctional phenols and carbonate donors;
- 2) aliphatic esters of carbonic acid or derivatives thereof, or aliphatic carboxylic acids or derivatives thereof and carbonate donors;
- and 3) mixtures thereof,
- wherein the ester component is at least 70% wt. % of the sum of the ester component and D;
- c) the aliphatic or partially aromatic polyester amides are prepared by reacting as starting materials, an ester or a mixture thereof as described in (a) with an amide component selected from the group consisting of
- E) an amide fraction of an amine component selected from the group consisting of aliphatic bifunctional amines, cycloaliphatic bifunctional amines, and mixtures thereof;
- and
- optional small amounts of branched bifunctional amines, higher-functional amines or mixture thereof;
- and
- an acid component selected from the group consisting of linear bifunctional acids, cycloaliphatic bifunctional acids, aromatic bifunctional acids, and mixtures thereof;
- and
- optional small amounts of branched bifunctional acids, higher-functional acids, and mixtures thereof;
- F) an amide fraction of compounds containing both amine and acid moieties;
- and mixtures thereof,
- wherein the ester component is at least 30 wt. % of the sum of the ester component and the amide component,
- and wherein all acids are optionally derivatized as moieties selected from the group consisting of acid chlorides, monomeric esters and oligomeric esters.
A process to adhesive bond a material comprising:
- applying a compostable water-resistant coating comprising 1 to 70 wt. % biodegradable polymers selected from the group consisting of aliphatic or partly aromatic polyesters, thermoplastic aliphatic or partly aromatic polyesterurethanes, aliphatic or aliphatic/aromatic polyestercarbonates and aliphatic or partly aromatic polyesteramides to the material;
- and evaporating the solvent.
Dependencies are inferred from the claim text.