Back to results
US 6,306,970 B1Granted
Soft propylene polymer blend with high melt strength
AssigneeMontell Technology Company BV
InventorsVu A. Dang, Dinshong Dong
Life of this patent
Estimating the term…
Abstract
A polymer blend having a high melt strength and a low Young's modulus after irradiation of the polymers contains (1) a propylene homopolymer or copolymer having an isotactic index of greater than 90 and (2) a propylene homopolymer or copolymer having a crystallinity of <24% made using a metallocene catalyst. The blend can be used for extrusion coating (including fabric coating), foam extrusion, blow molding, and thermoforming applications.
Claims6
A process for making an irradiated polymer blend comprising
- (1) preparing a blend comprising:
- (a) a propylene polymer selected from the group consisting of (i) a propylene homopolymer and (ii) a copolymer of propylene and ethylene or a 4-8 C alpha-olefin, wherein the content of polymerized ethylene or polymerized alpha-olefin is 10% or less, the propylene polymer having an isotactic index of greater than 90, and
- (b) a propylene polymer made using a metallocene catalyst and selected from the group consisting of (i) a propylene homopolymer and (ii) a copolymer of propylene and ethylene or a 4-8 C alpha-olefin, wherein the content of polymerized ethylene or polymerized alpha-olefin is 10% or less, the propylene polymer having a crystallinity of less than 24% measured from the heat of crystallization,
- (2) irradiating the blend in an environment in which the active oxygen concentration is established and maintained at less than 15% by volume with high energy ionizing radiation at a radiation dose of 3 to 12 Mrad for a period of time sufficient for a substantial amount of radical formation to occur, but insufficient to cause gelation of the material;
- (3) maintaining the irradiated material in such an environment for a period of up to two hours;
- and
- (4) treating the irradiated material while in such an environment to deactivate substantially all of the free radicals present in the irradiated material, whereby the irradiated blend has a melt tension of greater than 7 centiNewtons at 200° C. and a Young's modulus of less than 1000 MPa.
4 more elements
Dependencies are inferred from the claim text.