Color filters
AssigneeMitsui Chemicals, Inc.
InventorsHisato Itoh, Akio Karasawa, Kenichi Sugimoto
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Abstract
Dyes suitable for use in the fabrication of color filters are described which contain one or more photopolymerizable substituents preferably represented by the following formula: D—(A—Yn1)n2 (1) where D represents a chromphoric nucleus, A denotes a connecting group, Y means the photopolymerizable group, n1 is 1-10,000, and n2 stands for an integer of 1-10. Also described are photosensitive resist resin compositions containing the dyes as well as color filters fabricated by curing the photosensitive resist resin compositions.
Claims7
An LCD color filter fabricated by curing a photosensitive resist resin composition comprising:
- (A) 1-100 weight parts of at least one dye selected from the group consisting of the following dyes (a) or (c):
- (a) dyes containing a photopolymerizable substituent of the formula (1):
- D—(A—Yn1)n2 (1)
- wherein D is a chromophoric nucleus,
- A denotes a connecting group of one of the formulae (19) to (22), in which parenthesized recurring units may be combined together at random:
- wherein one of R26 and R27 represents a hydrogen atom and the other denotes a hydroxyl group;
- and r1 and s1 each stands for an integer of from 1-10,000;
- wherein R28 to R31 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a halogen atom;
- and r2 stands for an integer of from 1-10,000;
- wherein r3 stands for an integer of 1-10,000,
- wherein R32 to R37 independently represent a hydrogen atom, a halogen atom, a hydroxyl group, —SH, an amino group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxyl group, a substituted or unsubstituted alkylamino group, or a substituted or unsubstituted arylamino group;
- and a1, b1 and c1 each stands for an integer of from 0-10,000, Y is a photopolymerizable group of one of the formulae (2)-(7)
- wherein R1 to R4 independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aralkyl group, or a hydrogen atom;
- R5 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group, or a hydrogen atom;
- R5 is a hydrogen atom or a methyl group, provided that if R5 is a methyl group, then R5 is a hydrogen atom;
- and R6, R7 and R8 independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkoxy group, a halogen atom, or a hydrogen atom,
- n1 is 1-10,000 and n2 is 1-10,
- (c) dyes for color filters, said dyes having a molecular weight of at least 500 but not greater than 4000 and represented by the following formula (9):
- D—E—D (9)
- wherein D represents a chromophoric nucleus and E denotes a connecting group of one of the formulae —F—OCO—G—COO—F—, —F—COO—G—OOC—F—, —F—CONH—G—NHCO—F—, —F—OCONH—G—NHCOO—F— and —F—OCOO—G—OCOO—F— where F and G are divalent connecting groups selected from formulae (20) to (22) above in which r1 to r3, s1, a1, b1 and c1 each stands for an integer of from 1-100, or formula (23):
- wherein R38 to R49 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a halogen atom;
- R50 and R51 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a halogen atom;
- a2, b2, c2, a3, b3 and c3 each stands for an integer of from 0-100;
- and d stands for an integer of 1-5;
- and
- provided that each chromophoric nucleus D in formulae (1) and (9) is independently an anthraquinone, phthalocyanine, quinophthalone or pyridoneazo residue, and
- (B) 100 weight parts of a photosensitive resist resin.
Dependencies are inferred from the claim text.