Process for producing a pulp suitable for papermaking from nonwood fibrous materials
AssigneesNorth Carolina State University, HurterConsult Incorporated
InventorsRobert W. Hurter, Medwick V. Byrd, Jr.
Life of this patent
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Abstract
A process for producing a pulp suitable for papermaking from a nonwood fiber source material. Representative nonwood fiber source materials include corn stover and wheat straw. The process includes the steps of providing a nonwood fiber source material; digesting the nonwood fiber source material with an alkaline pulping solution at at least about atmospheric pressure; reducing the pH of the nonwood fiber source material to an acidic pH with an acid solution; treating the nonwood fiber source material having an acidic pH with ozone; and treating the nonwood fiber source material with a bleaching solution to form a papermaking pulp.
Claims64
A process for producing a pulp suitable for making paper from a nonwood fiber source material, the process comprising:
- (a) providing a nonwood fiber source material;
- (b) extracting the nonwood fiber source material with an alkaline pulping solution at at least about atmospheric pressure;
- (c) reducing the pH of the nonwood fiber source material pH formed in step (b) to an acidic pH with an acid solution;
- (d) treating the nonwood fiber source material having an acidic pH formed in step (c) with ozone;
- and
- (e) treating the nonwood fiber source material of step (d) with a bleaching solution comprising a bleaching agent different from the ozone of step (d) to form a papermaking pulp, wherein the pulp has a freeness level of at least 400 mL CSF or greater and a brightness level of at least 70% ISO.
A process for producing a pulp suitable for making paper from a nonwood fiber source material, the process comprising the sequential steps of:
- (a) providing a nonwood fiber source material;
- (b) extracting the nonwood fiber source material with an alkaline pulping solution for about 1 to about 90 minutes at a pressure ranging from about atmospheric pressure to about 30 psig and at a temperature ranging from about ambient temperature to about 150° C.;
- (c) treating the nonwood fiber source material with an acid solution at a temperature ranging from ambient temperature to about 90° C. and for a time ranging from about 30 to about 60 minutes to reduce the pH to an acidic pH;
- (d) dewatering the nonwood fiber source material to a consistency of at least about 35% and then diluting the nonwood fiber source material to a lower consistency ranging from about 1% to about 10%;
- (e) treating the nonwood fiber source material having an acidic pH with ozone;
- and
- (f) treating the nonwood fiber source material with a bleaching comprising a bleaching agent different from the ozone of step (e) to form a papermaking pulp having a Kappa value of at least as low as 5, a freeness level of at least 400 mL CSF or greater and a brightness level of at least 70% ISO.
A process for producing a pulp suitable for making paper from a nonwood fiber source material, the process comprising the sequential steps of:
- (a) providing a nonwood fiber source material;
- (b) extracting the nonwood fiber source material with an alkaline hydroxide pulping solution for about 30 to about 60 minutes at a pressure ranging from about atmospheric pressure to about 30 psig and at a temperature ranging from about 80° C. to about 120° C., wherein alkaline hydroxide in the alkaline hydroxide pulping solution is present in a dosage of ranging from about 10% weight to about 30% weight on ODF;
- (c) reducing the pH of the nonwood fiber source material to a pH ranging from about 1 to about 3 with an acid solution at a temperature ranging from about 50° C. to about 70° C. and for a time ranging from about 20 minutes to about 30 minutes;
- (d) dewatering the nonwood fiber source material to a consistency of at least about 35% and then diluting the nonwood fiber source material to a lower consistency ranging from about 1% to about 10%;
- (e) treating the nonwood fiber source material having an acidic pH with ozone at about ambient temperature for about 5 to about 15 minutes, wherein the ozone is present in a dosage ranging from about 0.4% weight to about 1% weight on ODF;
- (f) cleaning the nonwood fiber source material with at least one filtering screen;
- and
- (g) treating the nonwood fiber source material with a bleaching solution comprising a bleaching agent different from the ozone of step (e) at a temperature ranging from about 70° C. to about 110° C. to form a papermaking pulp having a Kappa value of at least as low as 5, a freeness level of at least 400 mL CSF or greater and a brightness level of at least 80% ISO.
The process of claim, 51, wherein the acid solution comprises an acid selected from the group consisting of a mineral acid, an organic acid and combinations thereof.
The process of claim, 51, wherein said treating the nonwood fiber source material having an acidic pH with ozone produces a pulp having a Kappa number of at least as low as 5.
Dependencies are inferred from the claim text.