# US 6,297,440 B1 · Thermoelectric device and method of making

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- Number: US 6,297,440 B1
- Document ID: US6297440B1
- Status: Granted
- Kind: B1
- Application number: 09/411,076
- Filed: 1999-10-04
- Granted: 2001-10-02
- Earliest claimed: 1997-06-10
- Assignees: USF Filtration and Separations Group, Inc.
- Inventors: Michael Liberman; Alexander Sobolevsky
- Web page: https://patentgrep.com/patent/US6297440B1

## CPC

- H10N 10/17: characterised by the structure or configuration of the cell or thermocouple forming the device
- H10N 10/01: Manufacture or treatment
- H10N: ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR

## Abstract

An apparatus and process for making a thermoelectric device for generating an electrical voltage when elevated in temperature. The apparatus comprises an array of a multiplicity of thermoelectric elements with each of the thermoelectric elements comprising a first metal component surrounded by a second metal component with a dielectric material interposed therebetween. A first connector interconnects the first metal components to form a first thermoelectric terminal. A second connector interconnects the second metal components to form a second thermoelectric terminal. A junction connector forms a multiplicity of thermoelectric junctions between the first metal components and the second metal components.

## Claims

### Claim 1

An improved thermoelectric device for generating an electrical voltage when elevated in temperature, comprising:
an array of a multiplicity of thermoelectric elements;
each of said multiplicity of said thermoelectric elements comprising a first metal component surrounded by a second metal component with a dielectric material interposed therebetween;
a first connector interconnecting each of said first metal components of said multiplicity of said thermoelectric elements to form a first thermoelectric terminal;
a second connector interconnecting each of said second metal components of said multiplicity of said thermoelectric elements to form a second thermoelectric terminal; and
a junction connector interconnecting each of said first metal components to said second metal components of said multiplicity of said thermoelectric elements to form a multiplicity of thermoelectric junctions thereby.

### Claim 2 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein each of said first metal components includes a metallic wire.

### Claim 3 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein each of said first metal components includes a metallic wire having a substantially circular cross-section.

### Claim 4 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein said dielectric material includes an oxide on each of said first metal components.

### Claim 5 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein said dielectric material includes a coating on each of said first metal components.

### Claim 6 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein each of said second metal components includes a metallic tube.

### Claim 7 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein each of said second metal components includes a continuous metallic tube disposed about each of said first metal components and said dielectric materials.

### Claim 8 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein said first thermoelectric terminal includes each of said first metal components having an exposed portion; and
said first thermoelectric terminal interconnecting each of said exposed portions of each of said multiplicity of said first metal components to form said first thermoelectric terminal.

### Claim 9 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein said second thermoelectric terminal includes said multiplicity of said thermoelectric elements being disposed within a metallic conduit and being in electrical contact therewith.

### Claim 10 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein said junction thermoelectric connector includes a third metal component interconnecting each of said first metal components to said second metal components to form said thermoelectric junction thereby.

### Claim 11 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein said junction thermoelectric connector includes a third metal component being the same metal as only one of said first and second metal components.

### Claim 12 (depends on 1)

An improved thermoelectric device as set forth in claim 1, including a terminal insulator for insulating said first thermoelectric terminal from said second thermoelectric terminal.

### Claim 13 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein said second connector interconnects all of said second metal components; and
said junction connector comprising a third metal component being the same material as said second metal component for interconnecting all of said first metal components to said second connector.

### Claim 14 (depends on 1)

An improved thermoelectric device as set forth in claim 1, wherein said junction connector interconnects said first metal components to said second metal components to form a multiplicity of thermoelectric junctions interconnected in electrical parallel.

### Claim 15

A process for making a thermoelectric device, comprising the steps of:
providing a first metal component;
covering the first metal component with a dielectric material;
encasing the first metal component and the dielectric material with a second metal component;
drawing the second metal component with the first metal component and the dielectric material therein for reducing the outer diameter thereof and for forming a thermoelectric element;
inserting a multiplicity of the thermoelectric elements within a metal conduit;
drawing the metal conduit with the multiplicity of the thermoelectric elements therein for reducing the outer diameter thereof and for electrically interconnecting the second metal components of the multiplicity of thermoelectric elements to form a second thermoelectric terminal;
interconnecting the first metal components of the multiplicity of thermoelectric elements to form a first thermoelectric terminal; and
interconnecting the multiplicity of the first metal components to the multiplicity of the second metal components with a junction connector to form a multiplicity of thermoelectric junctions thereby.

### Claim 16 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of providing a first metal component includes providing a first metal component in the form of a metallic wire.

### Claim 17 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of providing a first metal component includes providing a first metal component in the form of a metallic wire having a substantially circular cross-section.

### Claim 18 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of covering the first metal component with a dielectric material includes forming an oxide on the first metal component.

### Claim 19 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of covering the first metal component with a dielectric material includes coating the first metal component with a dielectric material.

### Claim 20 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of covering the first metal component with a dielectric material includes wrapping the first metal component with a dielectric material in the form of a dielectric cloth.

### Claim 21 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of covering the first metal component with a dielectric material includes covering the first metal component in the form of a metallic wire having a diameter of 0.01 cm to 0.2 cm with the dielectric material having a thickness of 0.005 cm-0.05 cm.

### Claim 22 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of encasing the first metal component and the dielectric material with a second metal component includes forming a continuous metal tube about the first metal component and the dielectric material.

### Claim 23 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of encasing the first metal component and the dielectric material with a second metal component includes encasing the first metal component and the dielectric material within a preformed metal tube.

### Claim 24 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of encasing the first metal component and the dielectric material with a second metal component includes encasing the first metal component and the dielectric material within a metal tube having different chemical properties than the chemical properties of the first metal component.

### Claim 25 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of inserting a multiplicity of the thermoelectric elements within the metal conduit includes forming a parallel array of the multiplicity of the thermoelectric elements; and
inserting the parallel array of the multiplicity of the thermoelectric elements within a preformed metallic conduit.

### Claim 26 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of inserting a multiplicity of the thermoelectric elements within the metal conduit includes forming a continuous metal conduit about the multiplicity of the thermoelectric elements.

### Claim 27 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of encasing the first metal components and the dielectric material with a second metal component include forming an array of a multiplicity of first metal components and the dielectric materials; and
simultaneously inserting the array of the multiplicity of the first metal components and the dielectric materials within a preformed metal tube.

### Claim 28 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of drawing the metal conduit for electrically interconnecting the multiplicity of the second metal components includes drawing the metal conduit for diffusion welding the second metal components to the metal conduit to form a substantially unitary material.

### Claim 29 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of interconnecting the multiplicity of the first metal components with the first thermoelectric terminal includes exposing a portion of each of the first metal components of the array of thermoelectric elements; and
interconnecting the exposed portion of each of the multiplicity of the first metal components with the first thermoelectric terminal.

### Claim 30 (depends on 15)

A process for making a thermoelectric device as set forth in claim 15, wherein the step of interconnecting the multiplicity of the first metal components with the first thermoelectric terminal includes exposing a portion of each of the first metal components of the array of thermoelectric elements by chemically removing a portion of each of the second metal components and a portion of each of the second thermoelectric terminal; and
interconnecting the exposed portion of each of the multiplicity of the first metal components with the first thermoelectric terminal.
