# US 6,296,744 B1 · Apparatus for the electrochemical treatment of a liquid medium > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 6,296,744 B1 - Document ID: US6296744B1 - Status: Granted - Kind: B1 - Application number: 09/331,547 - Filed: 1999-10-14 - Granted: 2001-10-02 - Earliest claimed: 1996-12-18 - Assignees: Sterilox Technologies International Limited - Inventors: Nougzar Djeiranishvili; Sergei Boutine; Gennadii Evseevich Meerkop - Web page: https://patentgrep.com/patent/US6296744B1 ## CPC - C02F 1/4674: {with halogen or compound of halogens, e.g. chlorine, bromine} - C02F 1/46104: {Devices therefor; Their operating or servicing} - C02F 1/4618: {for producing "ionised" acidic or basic water} - C02F 1/001: {Processes for the treatment of water whereby the filtration technique is of importance (C02F1/44 takes precedence; construction of filters in general B01D24/00 - B01D41/00)} - C02F 1/4672: {by electrooxydation} - C02F 2201/4611: Fluid flow - C02F 2201/46115: Electrolytic cell with membranes or diaphragms - C02F 2201/4618: Supplying or removing reactants or electrolyte - C02F 2201/46185: Recycling the cathodic or anodic feed - C02F 2209/04: Oxidation reduction potential [ORP] - C02F 2209/06: pH - C02F 2303/04: Disinfection - C02F 2303/185: The treatment agent being halogen or a halogenated compound - C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes) ## Abstract There is disclosed an apparatus for the electrochemical treatment of a liquid medium, which allows the production of a sterilizing solution as well as the decontamination and purification of liquid mediums from toxic organic substances and other impurities. The apparatus contains a diaphragm-shaped electrolytic midstream cell, a feed line for the liquid medium being processed, a cathodic outlet line for carrying the liquid medium out of the cathode chamber to a place of collection or discharge, an anodic outlet line for carrying the liquid medium out of the anode chamber into a catalytic reactor for breaking down active chlorine, an exit line for carrying the liquid medium to the place of collection, and a bypass line, an additional exit line and a flow switching device. The apparatus can also be equipped with a flow switching device, a connecting line, a midstream expansion tank, a purification filter and other components. ## Claims ### Claim 1 An apparatus for the electrolytic treatment of a liquid medium, the apparatus comprising an electrolytic cell having an anode chamber containing an anode and a cathode chamber containing a cathode, the chambers being separated from each other by a permeable membrane, a feed line for supplying the liquid medium to the anode and the cathode chambers, a cathodic outlet line for carrying liquid medium away from the cathode chamber to a discharge point, the cathodic outlet line having a consumption regulator positioned thereon, a catalytic reactor, a first anodic outlet line for carrying liquid medium away from the anode chamber and to the catalytic reactor, an exit line connected to the catalytic reactor for carrying liquid medium to a collection point, a second anodic outlet line for carrying the liquid medium away from the anode chamber and to the collection point while bypassing the catalytic reactor, the second anodic outlet line containing a consumption limiter and/or a normally-closed regulator valve or consumption regulator, and a flow switching device to which is connected the first anodic outlet line, an entry line to the catalytic reactor and an exit line to a discharge point. ### Claim 2 (depends on 1) An apparatus as claimed in claim 1, wherein a midstream expansion tank is provided on the first anodic outlet line in front of the flow switching device. ### Claim 3 (depends on 2) An apparatus as claimed in claim 2, wherein at least one purification filter is provided on the first anodic outlet line or on the exit line and/or on a connecting line by means of which the first anodic outlet line is connected to the cathode outlet line. ### Claim 4 (depends on 3) An apparatus as claimed in claim 3, wherein there is provided a water-jet pump measuring device having at least one midstream ejector chamber positioned on the feed line and/or on a connecting branch leading away therefrom, by means of which the feed line is connected to the cathode chamber, the ejector chamber having at least one nozzle for inward suction to which an auxiliary line with a consumption regulator and/or filter is connected, the outflow point thereof being connected to the anodic or cathodic outlet line or positioned in a reagent solution tank, or communicating with the atmosphere. ### Claim 5 (depends on 4) An apparatus as claimed in claim 4, wherein there is provided a device for measuring and controlling the pH and/or redox potential of the flow of processed liquid medium, the electrodes of this device being positioned at an end of the first anodic outlet line in front of the flow switching device. ### Claim 6 (depends on 1) An apparatus as claimed in claim 1, wherein the anode chamber of the electrolytic cell has an inlet for the feed line, an outlet to the first anodic outlet line, and an outlet to the second outlet line. ### Claim 7 (depends on 1) An apparatus as claimed in claim 1, wherein the electrolytic cell, which is either flat or cylindrical in form, has a vertical, horizontal or sloping working position. ### Claim 8 An apparatus for the electrolytic treatment of a liquid medium, the apparatus comprising an electrolytic cell having an anode chamber containing an anode and a cathode chamber containing a cathode, the chambers being separated from each other by a permeable membrane, a feed line for supplying the liquid medium to the anode chamber or the cathode chamber, a flow switching line for carrying liquid medium from the anode chamber or an outlet line thereof to the cathode chamber or vice versa, a cathodic outlet line for carrying liquid medium away from the cathode chamber to a discharge point, the cathodic outlet line having a consumption regulator positioned thereon, a catalytic reactor, a first anodic outlet line for carrying liquid medium away from the anode chamber and to the catalytic reactor, an exit line connected to the catalytic reactor for carrying liquid medium to a collection point, a second anodic outlet line for carrying the liquid medium away from the anode chamber and to the collection point while bypassing the catalytic reactor, the second anodic outlet line containing a consumption limiter and/or a normally-closed regulator valve or consumption regulator, and a flow switching device to which is connected the first anodic outlet line, an entry line to the catalytic reactor and an exit line to a discharge point. ### Claim 9 (depends on 8) An apparatus as claimed in claim 8, wherein a midstream expansion tank is provided on the first anodic outlet line in front of the flow switching device and/or on the flow switching line. ### Claim 10 (depends on 9) An apparatus as claimed in claim 9, wherein at least one purification filter is provided on the first anodic outlet line or on the exit line and/or on the flow switching line and/or on a connecting line by means of which the first anodic outlet line is connected to the cathode outlet line. ### Claim 11 (depends on 10) An apparatus as claimed in claim 10, wherein there is provided a water-jet pump measuring device having at least one midstream ejector chamber positioned on the feed line and/or on a connecting branch leading away therefrom and/or on the flow switching line, by means of which the feed line is connected to the cathode chamber, the ejector chamber having at least one nozzle for inward suction to which an auxiliary line with a consumption regulator and/or filter is connected, the outflow point thereof being connected to the anodic or cathodic outlet line or positioned in a reagent solution tank, or communicating with the atmosphere. ### Claim 12 (depends on 11) An apparatus as claimed in claim 11, wherein there is provided a device for measuring and controlling the pH and/or redox potential of the flow of processed liquid medium, the electrodes of this device being positioned at an end of the first anodic outlet line in front of the flow switching device. ### Claim 13 (depends on 9) An apparatus as claimed in claim 9, wherein there is provided a water-jet pump measuring device having at least one midstream ejector chamber positioned on the feed line and/or on a connecting branch leading away therefrom and/or on the flow switching line, by means of which the feed line is connected to the cathode chamber, the ejector chamber having at least one nozzle for inward suction to which an auxiliary line with a consumption regulator and/or filter is connected, the outflow point thereof being connected to the anodic or cathodic outlet line or positioned in a reagent solution tank, or communicating with the atmosphere. ### Claim 14 (depends on 8) An apparatus as claimed in claim 8, wherein the anode chamber of the electrolytic cell has an inlet for the feed line, an outlet to the first anodic outlet line, and an outlet to the second outlet line. ### Claim 15 (depends on 8) An apparatus as claimed in claim 8, wherein the electrolytic cell, which is either flat or cylindrical in form, has a vertical, horizontal or sloping working position.